Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde
New metal ion complexes were synthesized with the general formula; K[PtLCl4], [ReLCl4] and K[ML(Cl)2] where M = Pd(II), Cd(II), Zn(II) and Hg(II), from the Azo ligand (HL) [2-Hydroxy-3-((5-mercapto-1,3,4-thiadiazol-2-yl)diazenyl)-1-naphth aldehyde] (HL) the ligand was synthesized from (2-hydroxy-1-n...
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| Format: | Article |
| Language: | Arabic |
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College of Science for Women, University of Baghdad
2016-06-01
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| Series: | Baghdad Science Journal |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2795 |
| _version_ | 1818787001417072640 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | New metal ion complexes were synthesized with the general formula; K[PtLCl4], [ReLCl4] and K[ML(Cl)2] where M = Pd(II), Cd(II), Zn(II) and Hg(II), from the Azo ligand (HL) [2-Hydroxy-3-((5-mercapto-1,3,4-thiadiazol-2-yl)diazenyl)-1-naphth aldehyde] (HL) the ligand was synthesized from (2-hydroxy-1-naphthaldehyde) and (5-amino-1,3,4-thiadiazole-2-thiol). The ligand and its metal complexes are characterized by phisco- chemical spectroscopic techniques (FT.IR, UV-Vis and Mass spectra, elemental analysis, molar conductivity, Atomic Absorption, Chloride contain and magnetic susceptibility). The spectral data suggest that the (HL) behaves as a bidentate ligand in all complexes. These studies revealed tetrahedral geometries for all metal complexes, except square planar for Pd(II) complex and except octahedral geometry for Pt(IV) and Re(V) complexes. The study of complexes formation via molar ratio of (M:L) as (1:1). Theoretical treatment of this ligand and its metal complexes in gas phase using Hyper chem.8 was preformed. |
| first_indexed | 2024-12-18T14:00:50Z |
| format | Article |
| id | doaj.art-9a9b4443fe754163893cedef797f3110 |
| institution | Directory Open Access Journal |
| issn | 2078-8665 2411-7986 |
| language | Arabic |
| last_indexed | 2024-12-18T14:00:50Z |
| publishDate | 2016-06-01 |
| publisher | College of Science for Women, University of Baghdad |
| record_format | Article |
| series | Baghdad Science Journal |
| spelling | doaj.art-9a9b4443fe754163893cedef797f31102022-12-21T21:05:20ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862016-06-0113210.21123/bsj.13.2.105-114Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-NaphthaldehydeBaghdad Science JournalNew metal ion complexes were synthesized with the general formula; K[PtLCl4], [ReLCl4] and K[ML(Cl)2] where M = Pd(II), Cd(II), Zn(II) and Hg(II), from the Azo ligand (HL) [2-Hydroxy-3-((5-mercapto-1,3,4-thiadiazol-2-yl)diazenyl)-1-naphth aldehyde] (HL) the ligand was synthesized from (2-hydroxy-1-naphthaldehyde) and (5-amino-1,3,4-thiadiazole-2-thiol). The ligand and its metal complexes are characterized by phisco- chemical spectroscopic techniques (FT.IR, UV-Vis and Mass spectra, elemental analysis, molar conductivity, Atomic Absorption, Chloride contain and magnetic susceptibility). The spectral data suggest that the (HL) behaves as a bidentate ligand in all complexes. These studies revealed tetrahedral geometries for all metal complexes, except square planar for Pd(II) complex and except octahedral geometry for Pt(IV) and Re(V) complexes. The study of complexes formation via molar ratio of (M:L) as (1:1). Theoretical treatment of this ligand and its metal complexes in gas phase using Hyper chem.8 was preformed.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2795"Bidentate Ligand; Azo Ligand, Azo Complexes, Theoretical Treatment" |
| spellingShingle | Baghdad Science Journal Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde Baghdad Science Journal "Bidentate Ligand; Azo Ligand, Azo Complexes, Theoretical Treatment" |
| title | Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde |
| title_full | Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde |
| title_fullStr | Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde |
| title_full_unstemmed | Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde |
| title_short | Synthesis and Spectroscopic Characterization for Some Metal ion Complexes with 2-Hydroxy-3-((5-Mercapto-1,3,4-Thiadiazol-2-yl)Diazenyl)-1-Naphthaldehyde |
| title_sort | synthesis and spectroscopic characterization for some metal ion complexes with 2 hydroxy 3 5 mercapto 1 3 4 thiadiazol 2 yl diazenyl 1 naphthaldehyde |
| topic | "Bidentate Ligand; Azo Ligand, Azo Complexes, Theoretical Treatment" |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2795 |
| work_keys_str_mv | AT baghdadsciencejournal synthesisandspectroscopiccharacterizationforsomemetalioncomplexeswith2hydroxy35mercapto134thiadiazol2yldiazenyl1naphthaldehyde |