Molecular Switching through Chalcogen-Bond-Induced Isomerization of Binuclear (Diaminocarbene)Pd<sup>II</sup> Complexes

Molecular Switching through Chalcogen-Bond-Induced Isomerization of Binuclear (Diaminocarbene)Pd<sup>II</sup> Complexes

Binuclear diaminocarbene complexes, which form as a regioisomer mixture in the reaction between isocyanide–palladium(II) complex <i>cis</i>-[PdCl<sub>2</sub>(CNXyl)<sub>2</sub>] and 1,3-thiazol-2-amine, are able to exchange an anionic chloride ligand with other ha...

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Bibliographic Details
Main Authors:	Roman A. Popov, Alexander S. Novikov, Vitalii V. Suslonov, Vadim P. Boyarskiy
Format:	Article
Language:	English
Published:	MDPI AG 2023-06-01
Series:	Inorganics
Subjects:	chalcogen bonding (Diaminocarbene)Pd<sup>II</sup> complexes regioisomerization halogen-dependent equilibrium
Online Access:	https://www.mdpi.com/2304-6740/11/6/255

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