Influence of the angle of the two paraquat groups in the central benzene of the bisparaquat derivatives on complexation of a crown ether with bisparaquat derivatives(双百草枯衍生物中以苯为中心的两个百草枯基团的夹角对冠醚与双百草枯络合的影响)

Influence of the angle of the two paraquat groups in the central benzene of the bisparaquat derivatives on complexation of a crown ether with bisparaquat derivatives(双百草枯衍生物中以苯为中心的两个百草枯基团的夹角对冠醚与双百草枯络合的影响)

设计并合成了一种新颖的冠醚5和3种有着不同夹角（A180、A120和A60）的双百草枯衍生物.双百草枯衍生物中以苯为中心的两个百草枯基团间的夹角的作用表现为：冠醚5对类双百草枯的络合有着显著的影响.量子化学计算也论证了这一结果.冠醚5对上述3种类双百草枯有着选择性识别作用....

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Bibliographic Details
Main Authors: YEYu-yuan(叶余原), ZHENGRen-hua(郑人华), ZHONGAi-guo(钟爱国), HEBing-jing(何冰晶), CHENRen-er(陈仁尔), ZHOUQi-zhong(周其忠), JIANGHuajiang(蒋华江)
Format: Article
Language:zho
Published: Zhejiang University Press 2011-03-01
Series:Zhejiang Daxue xuebao. Lixue ban
Subjects:
冠醚
百草枯
夹角
络合
选择性识别
Online Access:https://doi.org/10.3785/j.issn.1008-9497.2011.02.017

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