Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride
In the title complex, [CoIIICl(C2H8N2)2(C2H3N3)]Cl2, the CoIII ion has a distorted octahedral environment. It is surrounded by four N atoms in the equatorial plane, with another N atom and a Cl atom occupying the axial positions. Both five-membered Co—N—C—C—N rings adopt a twist conformation. The Co...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-12-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461701728X |
| _version_ | 1828236713689874432 |
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| author | Y. AaminaNaaz S. Thirumurugan D. Venkatesh K. Anbalagan A. SubbiahPandi |
| author_facet | Y. AaminaNaaz S. Thirumurugan D. Venkatesh K. Anbalagan A. SubbiahPandi |
| author_sort | Y. AaminaNaaz |
| collection | DOAJ |
| description | In the title complex, [CoIIICl(C2H8N2)2(C2H3N3)]Cl2, the CoIII ion has a distorted octahedral environment. It is surrounded by four N atoms in the equatorial plane, with another N atom and a Cl atom occupying the axial positions. Both five-membered Co—N—C—C—N rings adopt a twist conformation. The Co—N bond lengths range from 1.941 (2) to 1.954 (1) Å, while the Co—Cl bond length is 2.257 (1) Å. In the crystal, molecules are linked by N—H...N, N—H...Cl and C—H...Cl hydrogen bonds. Dimers are formed by N—H...Cl hydrogen-bonding interactions between amine H-atom donors and chloride ions resulting in an R42(8) ring motif. These dimers are further connected in a head-to-tail fashion via N—H...Cl and C—H...Cl hydrogen bonds. All the interactions together combine to link the molecules into a three-dimensional framework. |
| first_indexed | 2024-04-12T20:37:11Z |
| format | Article |
| id | doaj.art-9ad33d110c9644a7970d9e755a60dea7 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-12T20:37:11Z |
| publishDate | 2017-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-9ad33d110c9644a7970d9e755a60dea72022-12-22T03:17:32ZengInternational Union of CrystallographyIUCrData2414-31462017-12-01212x17172810.1107/S241431461701728Xbt4067Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichlorideY. AaminaNaaz0S. Thirumurugan1D. Venkatesh2K. Anbalagan3A. SubbiahPandi4Department of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaIn the title complex, [CoIIICl(C2H8N2)2(C2H3N3)]Cl2, the CoIII ion has a distorted octahedral environment. It is surrounded by four N atoms in the equatorial plane, with another N atom and a Cl atom occupying the axial positions. Both five-membered Co—N—C—C—N rings adopt a twist conformation. The Co—N bond lengths range from 1.941 (2) to 1.954 (1) Å, while the Co—Cl bond length is 2.257 (1) Å. In the crystal, molecules are linked by N—H...N, N—H...Cl and C—H...Cl hydrogen bonds. Dimers are formed by N—H...Cl hydrogen-bonding interactions between amine H-atom donors and chloride ions resulting in an R42(8) ring motif. These dimers are further connected in a head-to-tail fashion via N—H...Cl and C—H...Cl hydrogen bonds. All the interactions together combine to link the molecules into a three-dimensional framework.http://scripts.iucr.org/cgi-bin/paper?S241431461701728Xcrystal structureethane-1,2-diaminetriazole ligandcobalt(III) complexhydrogen bondingN—H...NN—H...Cl and C—H...Cl interactions |
| spellingShingle | Y. AaminaNaaz S. Thirumurugan D. Venkatesh K. Anbalagan A. SubbiahPandi Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride IUCrData crystal structure ethane-1,2-diamine triazole ligand cobalt(III) complex hydrogen bonding N—H...N N—H...Cl and C—H...Cl interactions |
| title | Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride |
| title_full | Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride |
| title_fullStr | Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride |
| title_full_unstemmed | Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride |
| title_short | Chloridobis(ethane-1,2-diamine)(4H-1,2,4-triazole-κN1)cobalt(III) dichloride |
| title_sort | chloridobis ethane 1 2 diamine 4h 1 2 4 triazole κn1 cobalt iii dichloride |
| topic | crystal structure ethane-1,2-diamine triazole ligand cobalt(III) complex hydrogen bonding N—H...N N—H...Cl and C—H...Cl interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461701728X |
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