Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
The reaction between Ni(II), Co(II), cr(III) bitrates, Ni(II) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (BPPY) resulted in isolation of [Ni(BPPY)2](NO3)2.2H2O, [Ni(BPPY)2]Cl2, [Co(BPPY)2](NO3)2 and [Cr(BPPY)3](NO3)3; 2H2O. The compounds were characterized by elemental...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2000-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10202_3b460f20ac27e5e5157fe43b3151cee4.pdf |
| Summary: | The reaction between Ni(II), Co(II), cr(III) bitrates, Ni(II) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (BPPY) resulted in isolation of [Ni(BPPY)2](NO3)2.2H2O, [Ni(BPPY)2]Cl2, [Co(BPPY)2](NO3)2 and [Cr(BPPY)3](NO3)3; 2H2O. The compounds were characterized by elemental analyses and infrared 1HNMR spectroscopy, molar conductivity in solution and molecular weight measurements. |
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| ISSN: | 1021-9986 1021-9986 |