Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine

The reaction between Ni(II), Co(II), cr(III) bitrates, Ni(II) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (BPPY) resulted in isolation of [Ni(BPPY)2](NO3)2.2H2O, [Ni(BPPY)2]Cl2, [Co(BPPY)2](NO3)2 and [Cr(BPPY)3](NO3)3; 2H2O. The compounds were characterized by elemental...

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Main Authors: Ahmad Emad, Kazem Karami
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2000-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_10202_3b460f20ac27e5e5157fe43b3151cee4.pdf
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author Ahmad Emad
Kazem Karami
author_facet Ahmad Emad
Kazem Karami
author_sort Ahmad Emad
collection DOAJ
description The reaction between Ni(II), Co(II), cr(III) bitrates, Ni(II) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (BPPY) resulted in isolation of [Ni(BPPY)2](NO3)2.2H2O, [Ni(BPPY)2]Cl2, [Co(BPPY)2](NO3)2 and [Cr(BPPY)3](NO3)3; 2H2O. The compounds were characterized by elemental analyses and infrared 1HNMR spectroscopy, molar conductivity in solution and molecular weight measurements.
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spelling doaj.art-9afb6ff2f50543d3913fefc7a9c6216c2022-12-21T21:18:05ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862000-06-01191192310202Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with BenzoylamethylenetriphenylphosphineAhmad Emad0Kazem Karami1Department of Chemistry, Teacher Training University, Zip code 15614, Tehran, I.R. IRANDepartment of Chemistry, Teacher Training University, Zip code 15614, Tehran, I.R. IRANThe reaction between Ni(II), Co(II), cr(III) bitrates, Ni(II) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (BPPY) resulted in isolation of [Ni(BPPY)2](NO3)2.2H2O, [Ni(BPPY)2]Cl2, [Co(BPPY)2](NO3)2 and [Cr(BPPY)3](NO3)3; 2H2O. The compounds were characterized by elemental analyses and infrared 1HNMR spectroscopy, molar conductivity in solution and molecular weight measurements.http://www.ijcce.ac.ir/article_10202_3b460f20ac27e5e5157fe43b3151cee4.pdfcomplexbenzoylmethylenetriphenylphosphineni(ii)co(ii)cr(iii)
spellingShingle Ahmad Emad
Kazem Karami
Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
Iranian Journal of Chemistry & Chemical Engineering
complex
benzoylmethylenetriphenylphosphine
ni(ii)
co(ii)
cr(iii)
title Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
title_full Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
title_fullStr Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
title_full_unstemmed Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
title_short Preparation and Characterization of Ni(II), Co (II) and Cr(III) Complexes with Benzoylamethylenetriphenylphosphine
title_sort preparation and characterization of ni ii co ii and cr iii complexes with benzoylamethylenetriphenylphosphine
topic complex
benzoylmethylenetriphenylphosphine
ni(ii)
co(ii)
cr(iii)
url http://www.ijcce.ac.ir/article_10202_3b460f20ac27e5e5157fe43b3151cee4.pdf
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AT kazemkarami preparationandcharacterizationofniiicoiiandcriiicomplexeswithbenzoylamethylenetriphenylphosphine