Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (deter...
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Format: | Article |
Language: | English |
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De Gruyter
2013-06-01
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Series: | High Temperature Materials and Processes |
Subjects: | |
Online Access: | https://doi.org/10.1515/htmp-2012-0127 |
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author | Zhang Ligang Schmetterer Clemens Masset Patrick J. |
author_facet | Zhang Ligang Schmetterer Clemens Masset Patrick J. |
author_sort | Zhang Ligang |
collection | DOAJ |
description | The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (determined using drop calorimetry), were included in the optimization of the ternary phase diagram CaO-SiO2-K2O. |
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format | Article |
id | doaj.art-9b1182f8a790478b8fadf50e9cb5a501 |
institution | Directory Open Access Journal |
issn | 0334-6455 2191-0324 |
language | English |
last_indexed | 2024-12-17T22:03:26Z |
publishDate | 2013-06-01 |
publisher | De Gruyter |
record_format | Article |
series | High Temperature Materials and Processes |
spelling | doaj.art-9b1182f8a790478b8fadf50e9cb5a5012022-12-21T21:30:55ZengDe GruyterHigh Temperature Materials and Processes0334-64552191-03242013-06-0132322322810.1515/htmp-2012-0127Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) SystemsZhang Ligang0Schmetterer Clemens1Masset Patrick J.2Freiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, GermanyFreiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, GermanyFraunhofer UMSICHT-ATZ, An der Maxhütte 1, D-92237 Sulzbach-Rosenberg, GermanyThe aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (determined using drop calorimetry), were included in the optimization of the ternary phase diagram CaO-SiO2-K2O.https://doi.org/10.1515/htmp-2012-0127thermodynamicsphase diagrammodelingmolten slag |
spellingShingle | Zhang Ligang Schmetterer Clemens Masset Patrick J. Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems High Temperature Materials and Processes thermodynamics phase diagram modeling molten slag |
title | Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems |
title_full | Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems |
title_fullStr | Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems |
title_full_unstemmed | Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems |
title_short | Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems |
title_sort | thermodynamic modeling of the cao sio2 m2o m k na systems |
topic | thermodynamics phase diagram modeling molten slag |
url | https://doi.org/10.1515/htmp-2012-0127 |
work_keys_str_mv | AT zhangligang thermodynamicmodelingofthecaosio2m2omknasystems AT schmettererclemens thermodynamicmodelingofthecaosio2m2omknasystems AT massetpatrickj thermodynamicmodelingofthecaosio2m2omknasystems |