Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems

The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (deter...

Full description

Bibliographic Details
Main Authors: Zhang Ligang, Schmetterer Clemens, Masset Patrick J.
Format: Article
Language:English
Published: De Gruyter 2013-06-01
Series:High Temperature Materials and Processes
Subjects:
Online Access:https://doi.org/10.1515/htmp-2012-0127
_version_ 1818726767335047168
author Zhang Ligang
Schmetterer Clemens
Masset Patrick J.
author_facet Zhang Ligang
Schmetterer Clemens
Masset Patrick J.
author_sort Zhang Ligang
collection DOAJ
description The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (determined using drop calorimetry), were included in the optimization of the ternary phase diagram CaO-SiO2-K2O.
first_indexed 2024-12-17T22:03:26Z
format Article
id doaj.art-9b1182f8a790478b8fadf50e9cb5a501
institution Directory Open Access Journal
issn 0334-6455
2191-0324
language English
last_indexed 2024-12-17T22:03:26Z
publishDate 2013-06-01
publisher De Gruyter
record_format Article
series High Temperature Materials and Processes
spelling doaj.art-9b1182f8a790478b8fadf50e9cb5a5012022-12-21T21:30:55ZengDe GruyterHigh Temperature Materials and Processes0334-64552191-03242013-06-0132322322810.1515/htmp-2012-0127Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) SystemsZhang Ligang0Schmetterer Clemens1Masset Patrick J.2Freiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, GermanyFreiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, GermanyFraunhofer UMSICHT-ATZ, An der Maxhütte 1, D-92237 Sulzbach-Rosenberg, GermanyThe aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (determined using drop calorimetry), were included in the optimization of the ternary phase diagram CaO-SiO2-K2O.https://doi.org/10.1515/htmp-2012-0127thermodynamicsphase diagrammodelingmolten slag
spellingShingle Zhang Ligang
Schmetterer Clemens
Masset Patrick J.
Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
High Temperature Materials and Processes
thermodynamics
phase diagram
modeling
molten slag
title Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
title_full Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
title_fullStr Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
title_full_unstemmed Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
title_short Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems
title_sort thermodynamic modeling of the cao sio2 m2o m k na systems
topic thermodynamics
phase diagram
modeling
molten slag
url https://doi.org/10.1515/htmp-2012-0127
work_keys_str_mv AT zhangligang thermodynamicmodelingofthecaosio2m2omknasystems
AT schmettererclemens thermodynamicmodelingofthecaosio2m2omknasystems
AT massetpatrickj thermodynamicmodelingofthecaosio2m2omknasystems