Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes

Self-assembly nanofabrication is increasingly appealing in complex nanostructures, as it requires fewer materials and has potential to reduce feature sizes. The use of DNA to control nanoscale and microscale features is promising but not fully developed. In this work, we study self-assembled DNA nan...

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Main Authors: Dulashani R. Ranasinghe, Basu R. Aryal, Tyler R. Westover, Sisi Jia, Robert C. Davis, John N. Harb, Rebecca Schulman, Adam T. Woolley
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/25/20/4817
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author Dulashani R. Ranasinghe
Basu R. Aryal
Tyler R. Westover
Sisi Jia
Robert C. Davis
John N. Harb
Rebecca Schulman
Adam T. Woolley
author_facet Dulashani R. Ranasinghe
Basu R. Aryal
Tyler R. Westover
Sisi Jia
Robert C. Davis
John N. Harb
Rebecca Schulman
Adam T. Woolley
author_sort Dulashani R. Ranasinghe
collection DOAJ
description Self-assembly nanofabrication is increasingly appealing in complex nanostructures, as it requires fewer materials and has potential to reduce feature sizes. The use of DNA to control nanoscale and microscale features is promising but not fully developed. In this work, we study self-assembled DNA nanotubes to fabricate gold nanowires for use as interconnects in future nanoelectronic devices. We evaluate two approaches for seeding, gold and palladium, both using gold electroless plating to connect the seeds. These gold nanowires are characterized electrically utilizing electron beam induced deposition of tungsten and four-point probe techniques. Measured resistivity values for 15 successfully studied wires are between 9.3 × 10<sup>−6</sup> and 1.2 × 10<sup>−3</sup> Ωm. Our work yields new insights into reproducible formation and characterization of metal nanowires on DNA nanotubes, making them promising templates for future nanowires in complex electronic circuitry.
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spelling doaj.art-9b24910db8f64fd799dafdd9b0da9b982023-11-20T17:47:47ZengMDPI AGMolecules1420-30492020-10-012520481710.3390/molecules25204817Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA NanotubesDulashani R. Ranasinghe0Basu R. Aryal1Tyler R. Westover2Sisi Jia3Robert C. Davis4John N. Harb5Rebecca Schulman6Adam T. Woolley7Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602, USADepartment of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602, USADepartment of Physics and Astronomy, Brigham Young University, Provo, UT 84602, USAJohns Hopkins Institute for Nanobiotechnology, Johns Hopkins University, Baltimore, MD 21218, USADepartment of Physics and Astronomy, Brigham Young University, Provo, UT 84602, USADepartment of Chemical Engineering, Brigham Young University, Provo, UT 84602, USAJohns Hopkins Institute for Nanobiotechnology, Johns Hopkins University, Baltimore, MD 21218, USADepartment of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602, USASelf-assembly nanofabrication is increasingly appealing in complex nanostructures, as it requires fewer materials and has potential to reduce feature sizes. The use of DNA to control nanoscale and microscale features is promising but not fully developed. In this work, we study self-assembled DNA nanotubes to fabricate gold nanowires for use as interconnects in future nanoelectronic devices. We evaluate two approaches for seeding, gold and palladium, both using gold electroless plating to connect the seeds. These gold nanowires are characterized electrically utilizing electron beam induced deposition of tungsten and four-point probe techniques. Measured resistivity values for 15 successfully studied wires are between 9.3 × 10<sup>−6</sup> and 1.2 × 10<sup>−3</sup> Ωm. Our work yields new insights into reproducible formation and characterization of metal nanowires on DNA nanotubes, making them promising templates for future nanowires in complex electronic circuitry.https://www.mdpi.com/1420-3049/25/20/4817DNA-templated nanofabricationcurrent-voltage curvenanomaterialsresistivity
spellingShingle Dulashani R. Ranasinghe
Basu R. Aryal
Tyler R. Westover
Sisi Jia
Robert C. Davis
John N. Harb
Rebecca Schulman
Adam T. Woolley
Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
Molecules
DNA-templated nanofabrication
current-voltage curve
nanomaterials
resistivity
title Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
title_full Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
title_fullStr Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
title_full_unstemmed Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
title_short Seeding, Plating and Electrical Characterization of Gold Nanowires Formed on Self-Assembled DNA Nanotubes
title_sort seeding plating and electrical characterization of gold nanowires formed on self assembled dna nanotubes
topic DNA-templated nanofabrication
current-voltage curve
nanomaterials
resistivity
url https://www.mdpi.com/1420-3049/25/20/4817
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