Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window

We fabricated transparent and flexible silicon oxycarbide (SiOC) hard coating (HC) films on a colorless polyimide substrate to use as cover window films for flexible and foldable displays using a reactive roll-to-roll (R2R) sputtering system at room temperature. At a SiOC thickness of 100 nm, the R2...

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Main Authors: Jin-Hyeok Park, Chan-Hwi Kim, Ju-Hyeon Lee, Han-Ki Kim
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/12/3/233
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author Jin-Hyeok Park
Chan-Hwi Kim
Ju-Hyeon Lee
Han-Ki Kim
author_facet Jin-Hyeok Park
Chan-Hwi Kim
Ju-Hyeon Lee
Han-Ki Kim
author_sort Jin-Hyeok Park
collection DOAJ
description We fabricated transparent and flexible silicon oxycarbide (SiOC) hard coating (HC) films on a colorless polyimide substrate to use as cover window films for flexible and foldable displays using a reactive roll-to-roll (R2R) sputtering system at room temperature. At a SiOC thickness of 100 nm, the R2R-sputtered SiOC film showed a high optical transmittance of 87.43% at a visible range of 400 to 800 nm. The R2R-sputtered SiOC films also demonstrated outstanding flexibility, which is a key requirement of foldable and flexible displays. There were no cracks or surface defects on the SiOC films, even after bending (static folding), folding (dynamic folding), twisting, and rolling tests. Furthermore, the R2R-sputtered SiOC film showed good scratch resistance in a pencil hardness test (550 g) and steel wool test under a load of 250 g. To test the impact protection ability, we compared the performance of thin-film heaters (TFHs) and oxide-semiconductor-based thin-film transistors (TFTs) with and without SiOC cover films. The similar performance of the TFHs and TFTs with the SiOC cover window films demonstrate that the R2R-sputtered SiOC films offer promising cover window films for the next generation of flexible or foldable displays.
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spelling doaj.art-9b6cdfbeeb49484da3e01047621cbd652023-12-11T18:23:44ZengMDPI AGMicromachines2072-666X2021-02-0112323310.3390/mi12030233Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover WindowJin-Hyeok Park0Chan-Hwi Kim1Ju-Hyeon Lee2Han-Ki Kim3School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon-si, Gyeonggi-do 16419, KoreaSchool of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon-si, Gyeonggi-do 16419, KoreaSchool of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon-si, Gyeonggi-do 16419, KoreaSchool of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon-si, Gyeonggi-do 16419, KoreaWe fabricated transparent and flexible silicon oxycarbide (SiOC) hard coating (HC) films on a colorless polyimide substrate to use as cover window films for flexible and foldable displays using a reactive roll-to-roll (R2R) sputtering system at room temperature. At a SiOC thickness of 100 nm, the R2R-sputtered SiOC film showed a high optical transmittance of 87.43% at a visible range of 400 to 800 nm. The R2R-sputtered SiOC films also demonstrated outstanding flexibility, which is a key requirement of foldable and flexible displays. There were no cracks or surface defects on the SiOC films, even after bending (static folding), folding (dynamic folding), twisting, and rolling tests. Furthermore, the R2R-sputtered SiOC film showed good scratch resistance in a pencil hardness test (550 g) and steel wool test under a load of 250 g. To test the impact protection ability, we compared the performance of thin-film heaters (TFHs) and oxide-semiconductor-based thin-film transistors (TFTs) with and without SiOC cover films. The similar performance of the TFHs and TFTs with the SiOC cover window films demonstrate that the R2R-sputtered SiOC films offer promising cover window films for the next generation of flexible or foldable displays.https://www.mdpi.com/2072-666X/12/3/233SiOChard coating filmscolorless polyimideflexible and foldable displaysroll-to-toll sputtering
spellingShingle Jin-Hyeok Park
Chan-Hwi Kim
Ju-Hyeon Lee
Han-Ki Kim
Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
Micromachines
SiOC
hard coating films
colorless polyimide
flexible and foldable displays
roll-to-toll sputtering
title Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
title_full Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
title_fullStr Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
title_full_unstemmed Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
title_short Transparent and Flexible SiOC Films on Colorless Polyimide Substrate for Flexible Cover Window
title_sort transparent and flexible sioc films on colorless polyimide substrate for flexible cover window
topic SiOC
hard coating films
colorless polyimide
flexible and foldable displays
roll-to-toll sputtering
url https://www.mdpi.com/2072-666X/12/3/233
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AT chanhwikim transparentandflexiblesiocfilmsoncolorlesspolyimidesubstrateforflexiblecoverwindow
AT juhyeonlee transparentandflexiblesiocfilmsoncolorlesspolyimidesubstrateforflexiblecoverwindow
AT hankikim transparentandflexiblesiocfilmsoncolorlesspolyimidesubstrateforflexiblecoverwindow