Optimization of coagulation-flocculation parameters using a photometric dispersion analyser

The size and structural characteristics of floc particles are important design and control parameters in water treatment and should be rapidly monitored with a reasonable amount of accuracy. In this study, a photometric dispersion analyser (PDA) coupled to standard jar test experiments was used to o...

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Main Authors: S. R. Ramphal, M. S. Sibiya
Format: Article
Language:English
Published: Copernicus Publications 2014-07-01
Series:Drinking Water Engineering and Science
Online Access:http://www.drink-water-eng-sci.net/7/73/2014/dwes-7-73-2014.pdf
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author S. R. Ramphal
M. S. Sibiya
author_facet S. R. Ramphal
M. S. Sibiya
author_sort S. R. Ramphal
collection DOAJ
description The size and structural characteristics of floc particles are important design and control parameters in water treatment and should be rapidly monitored with a reasonable amount of accuracy. In this study, a photometric dispersion analyser (PDA) coupled to standard jar test experiments was used to optimize coagulation-flocculation parameters while monitoring floc size and structure as well as the rate of floc formation during coagulation using alum. The optimal coagulation conditions were as follows: sample pH 8; alum dosage, 3 mg L<sup>−1</sup> as Al<sup>3+</sup>; <i>G</i> value, 172 s<sup>−1</sup>; rapid mixing time, 20 s. These conditions resulted in unstable treated water having a calcium carbonate precipitation potential (CCPP) of −15 mg L<sup>−1</sup> as CaCO<sub>3</sub> and required a slaked lime dosage of 17 mg L<sup>−1</sup> as CaCO<sub>3</sub> to equilibrate CCPP to acceptable levels. PDA data revealed that aggregation rate and steady-state variance are primary parameters as both have substantial influence on coagulation-flocculation efficiency. However, the average steady state ratio, although an important parameter, had a lessened impact on coagulation-flocculation efficiency. The results of this study showed that the PDA instrument is an important tool in coagulation kinetic studies and can be employed as an additional tool in the optimization of coagulation conditions.
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spelling doaj.art-9b8dcd9b0d1744b4b910c724c82d6bf42022-12-21T20:01:20ZengCopernicus PublicationsDrinking Water Engineering and Science1996-94571996-94652014-07-0172738210.5194/dwes-7-73-2014Optimization of coagulation-flocculation parameters using a photometric dispersion analyserS. R. Ramphal0M. S. Sibiya1Rand Water, Process Technology Department, Glen Vista, South AfricaRand Water, Process Technology Department, Glen Vista, South AfricaThe size and structural characteristics of floc particles are important design and control parameters in water treatment and should be rapidly monitored with a reasonable amount of accuracy. In this study, a photometric dispersion analyser (PDA) coupled to standard jar test experiments was used to optimize coagulation-flocculation parameters while monitoring floc size and structure as well as the rate of floc formation during coagulation using alum. The optimal coagulation conditions were as follows: sample pH 8; alum dosage, 3 mg L<sup>−1</sup> as Al<sup>3+</sup>; <i>G</i> value, 172 s<sup>−1</sup>; rapid mixing time, 20 s. These conditions resulted in unstable treated water having a calcium carbonate precipitation potential (CCPP) of −15 mg L<sup>−1</sup> as CaCO<sub>3</sub> and required a slaked lime dosage of 17 mg L<sup>−1</sup> as CaCO<sub>3</sub> to equilibrate CCPP to acceptable levels. PDA data revealed that aggregation rate and steady-state variance are primary parameters as both have substantial influence on coagulation-flocculation efficiency. However, the average steady state ratio, although an important parameter, had a lessened impact on coagulation-flocculation efficiency. The results of this study showed that the PDA instrument is an important tool in coagulation kinetic studies and can be employed as an additional tool in the optimization of coagulation conditions.http://www.drink-water-eng-sci.net/7/73/2014/dwes-7-73-2014.pdf
spellingShingle S. R. Ramphal
M. S. Sibiya
Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
Drinking Water Engineering and Science
title Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
title_full Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
title_fullStr Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
title_full_unstemmed Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
title_short Optimization of coagulation-flocculation parameters using a photometric dispersion analyser
title_sort optimization of coagulation flocculation parameters using a photometric dispersion analyser
url http://www.drink-water-eng-sci.net/7/73/2014/dwes-7-73-2014.pdf
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