PECULIARITIES OF HIGH-RESOLUTION NUCLEAR MAGNETIC RESONANCE IN PARAMAGNETIC COMPLEXES OF ELEMENTS OF THE FIRST TRANSITION GROUP
The paper lists the peculiarities of nuclear magnetic resonance in paramagnetic systems. The character of relaxation processes with spins of unpaired electrons is discussed. The author analyzes the specifics of detecting high-resolution nuclear magnetic resonance spectra transformed by hyperfine int...
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| Format: | Article |
| Language: | English |
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Kemerovo State University
2015-02-01
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| Series: | Вестник Кемеровского государственного университета |
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| Online Access: | https://vestnik.kemsu.ru/jour/article/view/398 |
| Summary: | The paper lists the peculiarities of nuclear magnetic resonance in paramagnetic systems. The character of relaxation processes with spins of unpaired electrons is discussed. The author analyzes the specifics of detecting high-resolution nuclear magnetic resonance spectra transformed by hyperfine interaction. Particular examples are provided to illustrate the opportunities of using specific nuclear magnetic resonance in paramagnetic systems for studying the composition and dynamics of paramagnetic complexes, mostly elements of the first transition group. The author notes the necessity of further researches directed at expanding our knowledge of the character of electronic-nuclear interactions in paramagnetic systems of different nature. |
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| ISSN: | 2078-8975 2078-8983 |