Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles

Abstract To study the effect of nano‐silica particles on the conductivity characteristics of ethylene propylene diene monomer (EPDM) insulation, EPDM nanocomposites with different mass fractions of nano silica were prepared via the melt‐blending method. Scanning electron microscopy was used to analy...

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Main Authors: Chunyu Xu, Ruixue Zhao, Chuanyang Li, Yuanyuan Li, Guodong Zhang, Tohid Shahsavarian, Mengqiang Yuan, Zhipeng Lei
Format: Article
Language:English
Published: Wiley 2021-06-01
Series:High Voltage
Subjects:
Online Access:https://doi.org/10.1049/hve2.12070
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author Chunyu Xu
Ruixue Zhao
Chuanyang Li
Yuanyuan Li
Guodong Zhang
Tohid Shahsavarian
Mengqiang Yuan
Zhipeng Lei
author_facet Chunyu Xu
Ruixue Zhao
Chuanyang Li
Yuanyuan Li
Guodong Zhang
Tohid Shahsavarian
Mengqiang Yuan
Zhipeng Lei
author_sort Chunyu Xu
collection DOAJ
description Abstract To study the effect of nano‐silica particles on the conductivity characteristics of ethylene propylene diene monomer (EPDM) insulation, EPDM nanocomposites with different mass fractions of nano silica were prepared via the melt‐blending method. Scanning electron microscopy was used to analyze the dispersion of nanoparticles in EPDM. Based on the Fourier‐transform infrared spectrum, the bonding properties between the nanoparticles and EPDM were analyzed. The steady‐state current at 30–100 °C and 1–20 kV/mm was measured. Moreover, the conductivity characteristic was analyzed. The experimental results show that as the content of nano‐silica increases, the electrical conductivity of EPDM nanocomposite as well as the threshold field strength gradually decreases. Samples with a small number of nanoparticles will increase the activation energy of the carrier conductivity, and the interface region effect introduced by nanoparticles will reduce the carrier mobility and concentration, resulting in a lower conductivity. Comparing the calculated value of the dielectric constant with the measured value can conclude that the high‐field conductance process is a combination of the electrode effect and the body effect, which in this case, Schottky effect dominates.
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spelling doaj.art-9baad1ac136b4768909e17c21d64a4182022-12-22T02:49:47ZengWileyHigh Voltage2397-72642021-06-016348749410.1049/hve2.12070Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particlesChunyu Xu0Ruixue Zhao1Chuanyang Li2Yuanyuan Li3Guodong Zhang4Tohid Shahsavarian5Mengqiang Yuan6Zhipeng Lei7Shanxi Key Laboratory of Mining Electrical Equipment and Intelligent Control College of Electrical and Power Engineering Taiyuan University of Technology Taiyuan ChinaShanxi Key Laboratory of Mining Electrical Equipment and Intelligent Control College of Electrical and Power Engineering Taiyuan University of Technology Taiyuan ChinaElectrical and Computer Engineering University of Connecticut Storrs Connecticut USAShanxi Key Laboratory of Mining Electrical Equipment and Intelligent Control College of Electrical and Power Engineering Taiyuan University of Technology Taiyuan ChinaState Grid Jincheng Power Supply Company Jincheng ChinaElectrical and Computer Engineering University of Connecticut Storrs Connecticut USASchool of Electrical Engineering Shandong University Jinan ChinaShanxi Key Laboratory of Mining Electrical Equipment and Intelligent Control College of Electrical and Power Engineering Taiyuan University of Technology Taiyuan ChinaAbstract To study the effect of nano‐silica particles on the conductivity characteristics of ethylene propylene diene monomer (EPDM) insulation, EPDM nanocomposites with different mass fractions of nano silica were prepared via the melt‐blending method. Scanning electron microscopy was used to analyze the dispersion of nanoparticles in EPDM. Based on the Fourier‐transform infrared spectrum, the bonding properties between the nanoparticles and EPDM were analyzed. The steady‐state current at 30–100 °C and 1–20 kV/mm was measured. Moreover, the conductivity characteristic was analyzed. The experimental results show that as the content of nano‐silica increases, the electrical conductivity of EPDM nanocomposite as well as the threshold field strength gradually decreases. Samples with a small number of nanoparticles will increase the activation energy of the carrier conductivity, and the interface region effect introduced by nanoparticles will reduce the carrier mobility and concentration, resulting in a lower conductivity. Comparing the calculated value of the dielectric constant with the measured value can conclude that the high‐field conductance process is a combination of the electrode effect and the body effect, which in this case, Schottky effect dominates.https://doi.org/10.1049/hve2.12070carrier mobilityelectrical conductivityethylene‐propylene rubbernanocompositesnanofabricationnanoparticles
spellingShingle Chunyu Xu
Ruixue Zhao
Chuanyang Li
Yuanyuan Li
Guodong Zhang
Tohid Shahsavarian
Mengqiang Yuan
Zhipeng Lei
Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
High Voltage
carrier mobility
electrical conductivity
ethylene‐propylene rubber
nanocomposites
nanofabrication
nanoparticles
title Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
title_full Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
title_fullStr Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
title_full_unstemmed Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
title_short Significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano‐SiO2 particles
title_sort significant enhancement in the electrical conductance properties of ethylene propylene diene monomer using the nano sio2 particles
topic carrier mobility
electrical conductivity
ethylene‐propylene rubber
nanocomposites
nanofabrication
nanoparticles
url https://doi.org/10.1049/hve2.12070
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