Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler
Mercury is harmful to humans and the ecological environment. The adsorption process is known as an effective method for removing heavy metals. This research is devoted to developing new adsorbents based on carbon materials to remove metal ions Hg(II) with carbon-based monolith adsorbents without and...
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| Format: | Article |
| Language: | English |
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Universitas Syiah Kuala, Chemical Engineering Department
2022-12-01
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| Series: | Jurnal Rekayasa Kimia & Lingkungan |
| Subjects: | |
| Online Access: | https://jurnal.usk.ac.id/RKL/article/view/27747 |
| _version_ | 1797228446990991360 |
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| author | Debby Widya Kusuma Mahidin Mahidin darmadi darmadi |
| author_facet | Debby Widya Kusuma Mahidin Mahidin darmadi darmadi |
| author_sort | Debby Widya Kusuma |
| collection | DOAJ |
| description | Mercury is harmful to humans and the ecological environment. The adsorption process is known as an effective method for removing heavy metals. This research is devoted to developing new adsorbents based on carbon materials to remove metal ions Hg(II) with carbon-based monolith adsorbents without and with manganese oxide fillers (KM and KMM). The results of adsorption efficiency, adsorption kinetics, and isotherm models were made in a batch system with varying concentrations of mercury solution from 2 mg/L to 6 mg/L with adsorbents without and with manganese oxide fillers (KM and KMM). The highest removal efficiency reached 96% on KMM and 47% on KM. The adsorption isotherm of Hg(II) ions corresponds to the Freundlich model, with intensity and volume constants obtained respectively 0.042 and 1.347 L/mg on KM adsorbents, while on KMM adsorbents the intensity and volume constants obtained are 0.291 and 2.079, respectively. L/mg. These results indicate that physical adsorption occurs more dominantly than chemical adsorption. The adsorption of Hg(II) ions was in accordance with the pseudo-first-order adsorption kinetics, with the adsorption capacity and rate constant on the KM adsorbent obtained were 0.0505 mg/g and 0.0072 g/mg, while the adsorption capacity and rate constant for the KMM adsorbent were on KM adsorbents obtained were 0.0848 mg/g and 0.0239 g/mg. |
| first_indexed | 2024-03-13T00:14:39Z |
| format | Article |
| id | doaj.art-9bad8fd88bca484da0062a36282c0227 |
| institution | Directory Open Access Journal |
| issn | 1412-5064 2356-1661 |
| language | English |
| last_indexed | 2024-04-24T14:56:50Z |
| publishDate | 2022-12-01 |
| publisher | Universitas Syiah Kuala, Chemical Engineering Department |
| record_format | Article |
| series | Jurnal Rekayasa Kimia & Lingkungan |
| spelling | doaj.art-9bad8fd88bca484da0062a36282c02272024-04-02T18:28:44ZengUniversitas Syiah Kuala, Chemical Engineering DepartmentJurnal Rekayasa Kimia & Lingkungan1412-50642356-16612022-12-0117212112810.23955/rkl.v17i2.2774714986Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide FillerDebby Widya Kusuma0Mahidin Mahidin1darmadi darmadi2Universitas Syiah KualaUniversitas Syiah KualaUniversitas Syiah KualaMercury is harmful to humans and the ecological environment. The adsorption process is known as an effective method for removing heavy metals. This research is devoted to developing new adsorbents based on carbon materials to remove metal ions Hg(II) with carbon-based monolith adsorbents without and with manganese oxide fillers (KM and KMM). The results of adsorption efficiency, adsorption kinetics, and isotherm models were made in a batch system with varying concentrations of mercury solution from 2 mg/L to 6 mg/L with adsorbents without and with manganese oxide fillers (KM and KMM). The highest removal efficiency reached 96% on KMM and 47% on KM. The adsorption isotherm of Hg(II) ions corresponds to the Freundlich model, with intensity and volume constants obtained respectively 0.042 and 1.347 L/mg on KM adsorbents, while on KMM adsorbents the intensity and volume constants obtained are 0.291 and 2.079, respectively. L/mg. These results indicate that physical adsorption occurs more dominantly than chemical adsorption. The adsorption of Hg(II) ions was in accordance with the pseudo-first-order adsorption kinetics, with the adsorption capacity and rate constant on the KM adsorbent obtained were 0.0505 mg/g and 0.0072 g/mg, while the adsorption capacity and rate constant for the KMM adsorbent were on KM adsorbents obtained were 0.0848 mg/g and 0.0239 g/mg.https://jurnal.usk.ac.id/RKL/article/view/27747carbonmanganese oxidemonolithmercuryisoterm |
| spellingShingle | Debby Widya Kusuma Mahidin Mahidin darmadi darmadi Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler Jurnal Rekayasa Kimia & Lingkungan carbon manganese oxide monolith mercury isoterm |
| title | Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler |
| title_full | Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler |
| title_fullStr | Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler |
| title_full_unstemmed | Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler |
| title_short | Adsorption of Mercury (II) Ions from Water Using Carbon-Based Monolith with Manganese Oxide Filler |
| title_sort | adsorption of mercury ii ions from water using carbon based monolith with manganese oxide filler |
| topic | carbon manganese oxide monolith mercury isoterm |
| url | https://jurnal.usk.ac.id/RKL/article/view/27747 |
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