Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations
Cu II -arginine coordination compound was synthesized and characterized by using DSC, DTA, EA, FT-IR, XRD, SEM and EDX analysis techniques and then the hydrogen storage properties were investigated. Hydrogen storage performance of synthesized compound was determined both experimental and theoreti...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Hitit University
2014-12-01
|
| Series: | Hittite Journal of Science and Engineering |
| Subjects: | |
| Online Access: | https://dergipark.org.tr/tr/download/article-file/1506963 |
| _version_ | 1827796243774963712 |
|---|---|
| author | Zeynel Ozturk Abdurrahman Asan Goksel Ozkan Dursun Ali Kose |
| author_facet | Zeynel Ozturk Abdurrahman Asan Goksel Ozkan Dursun Ali Kose |
| author_sort | Zeynel Ozturk |
| collection | DOAJ |
| description | Cu II -arginine coordination compound was synthesized and characterized by using DSC, DTA, EA, FT-IR, XRD, SEM and EDX analysis techniques and then the hydrogen storage properties were investigated. Hydrogen storage performance of synthesized compound was determined both experimental and theoretically by using Materials Studio which is one of the Molecular simulation software and adsorption measurement equipment. It is found out that the arginine compound uptakes approximately 1.2 wt. % experimentally and 0.8 wt. % theoretically hydrogen in 77K and 100 bars pressure. Also the surface characteristics was calculated and also the possible cites which could uptake hydrogen in a single lattice cell were determined. At the end of this research, in addition to drug and other applications of L-arginine, it is proved that could be used as a part of adsorbent for hydrogen storage application. |
| first_indexed | 2024-03-11T19:03:33Z |
| format | Article |
| id | doaj.art-9bf9a90e3efc410786a2e20aac6b9387 |
| institution | Directory Open Access Journal |
| issn | 2148-4171 |
| language | English |
| last_indexed | 2024-03-11T19:03:33Z |
| publishDate | 2014-12-01 |
| publisher | Hitit University |
| record_format | Article |
| series | Hittite Journal of Science and Engineering |
| spelling | doaj.art-9bf9a90e3efc410786a2e20aac6b93872023-10-10T11:17:26ZengHitit UniversityHittite Journal of Science and Engineering2148-41712014-12-01111510.17350/HJSE19030000001150Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculationsZeynel Ozturk0Abdurrahman Asan1Goksel Ozkan2Dursun Ali Kose3Hitit University, Department of Chemical Engineering, Corum, TURKEYHitit University, Department of Chemical Engineering, Corum, TURKEYGazi University, Department of Chemical Engineering, Ankara, TURKEYHitit University, Alternative Energy Systems and Biomedical Research Centre, Corum, TURKEYCu II -arginine coordination compound was synthesized and characterized by using DSC, DTA, EA, FT-IR, XRD, SEM and EDX analysis techniques and then the hydrogen storage properties were investigated. Hydrogen storage performance of synthesized compound was determined both experimental and theoretically by using Materials Studio which is one of the Molecular simulation software and adsorption measurement equipment. It is found out that the arginine compound uptakes approximately 1.2 wt. % experimentally and 0.8 wt. % theoretically hydrogen in 77K and 100 bars pressure. Also the surface characteristics was calculated and also the possible cites which could uptake hydrogen in a single lattice cell were determined. At the end of this research, in addition to drug and other applications of L-arginine, it is proved that could be used as a part of adsorbent for hydrogen storage application.https://dergipark.org.tr/tr/download/article-file/1506963hydrogen storagecu-ii compoundl-argininecoordination compoundmolecular simulation. |
| spellingShingle | Zeynel Ozturk Abdurrahman Asan Goksel Ozkan Dursun Ali Kose Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations Hittite Journal of Science and Engineering hydrogen storage cu-ii compound l-arginine coordination compound molecular simulation. |
| title | Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations |
| title_full | Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations |
| title_fullStr | Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations |
| title_full_unstemmed | Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations |
| title_short | Porous metal-organic Cu II complex of L-Arginine; synthesis, characterization, hydrogen storage properties and molecular simulation calculations |
| title_sort | porous metal organic cu ii complex of l arginine synthesis characterization hydrogen storage properties and molecular simulation calculations |
| topic | hydrogen storage cu-ii compound l-arginine coordination compound molecular simulation. |
| url | https://dergipark.org.tr/tr/download/article-file/1506963 |
| work_keys_str_mv | AT zeynelozturk porousmetalorganiccuiicomplexoflargininesynthesischaracterizationhydrogenstoragepropertiesandmolecularsimulationcalculations AT abdurrahmanasan porousmetalorganiccuiicomplexoflargininesynthesischaracterizationhydrogenstoragepropertiesandmolecularsimulationcalculations AT gokselozkan porousmetalorganiccuiicomplexoflargininesynthesischaracterizationhydrogenstoragepropertiesandmolecularsimulationcalculations AT dursunalikose porousmetalorganiccuiicomplexoflargininesynthesischaracterizationhydrogenstoragepropertiesandmolecularsimulationcalculations |