Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite
In this paper, the Ni/NiO ultrathin nanobelts were successively synthesized by a facile in suit conversion process using pre-synthesized Ni-based metal-organic frameworks (MOFs) nanobelts as parent materials to detect the nitrite (NaNO2). The synthesized Ni/NiO composites have the advantages in stru...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2020-04-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2020.00330/full |
| _version_ | 1818023747595010048 |
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| author | Xiangren Meng Xiangren Meng Xiao Xiao Huan Pang |
| author_facet | Xiangren Meng Xiangren Meng Xiao Xiao Huan Pang |
| author_sort | Xiangren Meng |
| collection | DOAJ |
| description | In this paper, the Ni/NiO ultrathin nanobelts were successively synthesized by a facile in suit conversion process using pre-synthesized Ni-based metal-organic frameworks (MOFs) nanobelts as parent materials to detect the nitrite (NaNO2). The synthesized Ni/NiO composites have the advantages in structure, as follows: (I) Interleaved 3D reticulated structure has strong mechanical stability; (II) Ultrathin nanobelt structures allow more active sites to be exposed and make the transfer of charge faster; (III) A large number of ultrafine Ni nanoparticles decorate the building blocks of the NiO nanobelt and enhance the electrical conductivity. Ni/NiO/GCE has an obvious oxidation peak at 0.78 V, when the concentration is between 0.5 and 1000 μM, the oxidation peak current of NaNO2 is linearly related to the concentration, and the sensitivity is 1.5319 μA mM−1 cm−2 (S/N = 3). Moreover, the experimental results also concluded that the Ni/NiO ultrathin nanobelts not only indicated wonderful reproducibility in the determination of NaNO2 in the pickled pork samples, but also could be well-recovered and keep stable for a long time. |
| first_indexed | 2024-12-10T03:49:14Z |
| format | Article |
| id | doaj.art-9bfc1feb08754b11b9d8458b69ebebf4 |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-12-10T03:49:14Z |
| publishDate | 2020-04-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-9bfc1feb08754b11b9d8458b69ebebf42022-12-22T02:03:18ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462020-04-01810.3389/fchem.2020.00330535270Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of NitriteXiangren Meng0Xiangren Meng1Xiao Xiao2Huan Pang3School of Tourism and Culinary Science, Yangzhou University, Yangzhou, ChinaJiangsu Huai-yang Cuisine Engineering Center, Yangzhou University, Yangzhou, ChinaSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, ChinaSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, ChinaIn this paper, the Ni/NiO ultrathin nanobelts were successively synthesized by a facile in suit conversion process using pre-synthesized Ni-based metal-organic frameworks (MOFs) nanobelts as parent materials to detect the nitrite (NaNO2). The synthesized Ni/NiO composites have the advantages in structure, as follows: (I) Interleaved 3D reticulated structure has strong mechanical stability; (II) Ultrathin nanobelt structures allow more active sites to be exposed and make the transfer of charge faster; (III) A large number of ultrafine Ni nanoparticles decorate the building blocks of the NiO nanobelt and enhance the electrical conductivity. Ni/NiO/GCE has an obvious oxidation peak at 0.78 V, when the concentration is between 0.5 and 1000 μM, the oxidation peak current of NaNO2 is linearly related to the concentration, and the sensitivity is 1.5319 μA mM−1 cm−2 (S/N = 3). Moreover, the experimental results also concluded that the Ni/NiO ultrathin nanobelts not only indicated wonderful reproducibility in the determination of NaNO2 in the pickled pork samples, but also could be well-recovered and keep stable for a long time.https://www.frontiersin.org/article/10.3389/fchem.2020.00330/fullin suit conversion methodNi/NiO ultrathin nanobeltmetal nanoparticlemetal organic frameworknitrite |
| spellingShingle | Xiangren Meng Xiangren Meng Xiao Xiao Huan Pang Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite Frontiers in Chemistry in suit conversion method Ni/NiO ultrathin nanobelt metal nanoparticle metal organic framework nitrite |
| title | Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite |
| title_full | Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite |
| title_fullStr | Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite |
| title_full_unstemmed | Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite |
| title_short | Ultrathin Ni-MOF Nanobelts-Derived Composite for High Sensitive Detection of Nitrite |
| title_sort | ultrathin ni mof nanobelts derived composite for high sensitive detection of nitrite |
| topic | in suit conversion method Ni/NiO ultrathin nanobelt metal nanoparticle metal organic framework nitrite |
| url | https://www.frontiersin.org/article/10.3389/fchem.2020.00330/full |
| work_keys_str_mv | AT xiangrenmeng ultrathinnimofnanobeltsderivedcompositeforhighsensitivedetectionofnitrite AT xiangrenmeng ultrathinnimofnanobeltsderivedcompositeforhighsensitivedetectionofnitrite AT xiaoxiao ultrathinnimofnanobeltsderivedcompositeforhighsensitivedetectionofnitrite AT huanpang ultrathinnimofnanobeltsderivedcompositeforhighsensitivedetectionofnitrite |