Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations
Solid solutions (SS) of 3- and 4-component systems based on lead titanate-zirconate were prepared by the method of solid-phase reactions and uniaxial hot pressing. The dependences of the relative permittivity of polarized samples on the electronegativity (EN) of their constituent cations have been s...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
World Scientific Publishing
2022-08-01
|
| Series: | Journal of Advanced Dielectrics |
| Subjects: | |
| Online Access: | https://www.worldscientific.com/doi/10.1142/S2010135X22440040 |
| _version_ | 1817992236591218688 |
|---|---|
| author | Andryushin Konstantin Dudkina Svetlana Shilkina Lidiya Sahoo Sushrisangita Moysa Maksim Andryushina Inna Verbenko Iliya Reznichenko Larisa |
| author_facet | Andryushin Konstantin Dudkina Svetlana Shilkina Lidiya Sahoo Sushrisangita Moysa Maksim Andryushina Inna Verbenko Iliya Reznichenko Larisa |
| author_sort | Andryushin Konstantin |
| collection | DOAJ |
| description | Solid solutions (SS) of 3- and 4-component systems based on lead titanate-zirconate were prepared by the method of solid-phase reactions and uniaxial hot pressing. The dependences of the relative permittivity of polarized samples on the electronegativity (EN) of their constituent cations have been studied. The ferro-hardness of the SS (the stability of the domain structure to external influences) is shown to be directly dependent on the EN of elements B in the corresponding oxidation states, i.e., the degree of covalence of the B–O bond. The deviation from this dependence in SS with Ni and Cd is explained by their individual features, which result in changes in the degree of bond covalence in both cationic sublattices. The conducted crystal-chemical analysis made it possible to choose promising SS when creating ferroelectric materials, including textured piezoelectric ceramic materials for piezoelectric transducers for various purposes: Piezotransformers, piezoelectric motors, ultrasonic emitters, filter devices, ultrasonic flaw detectors, accelerometers, etc. |
| first_indexed | 2024-04-14T01:23:43Z |
| format | Article |
| id | doaj.art-9c0f641f13834d728cdb33ae3c701c57 |
| institution | Directory Open Access Journal |
| issn | 2010-135X 2010-1368 |
| language | English |
| last_indexed | 2024-04-14T01:23:43Z |
| publishDate | 2022-08-01 |
| publisher | World Scientific Publishing |
| record_format | Article |
| series | Journal of Advanced Dielectrics |
| spelling | doaj.art-9c0f641f13834d728cdb33ae3c701c572022-12-22T02:20:33ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682022-08-01120410.1142/S2010135X22440040Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cationsAndryushin Konstantin0Dudkina Svetlana1Shilkina Lidiya2Sahoo Sushrisangita3Moysa Maksim4Andryushina Inna5Verbenko Iliya6Reznichenko Larisa7Research Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaResearch Institute of Physics, Southern Federal University, Stachki str. 194, Rostov-on-Don 344090, RussiaSolid solutions (SS) of 3- and 4-component systems based on lead titanate-zirconate were prepared by the method of solid-phase reactions and uniaxial hot pressing. The dependences of the relative permittivity of polarized samples on the electronegativity (EN) of their constituent cations have been studied. The ferro-hardness of the SS (the stability of the domain structure to external influences) is shown to be directly dependent on the EN of elements B in the corresponding oxidation states, i.e., the degree of covalence of the B–O bond. The deviation from this dependence in SS with Ni and Cd is explained by their individual features, which result in changes in the degree of bond covalence in both cationic sublattices. The conducted crystal-chemical analysis made it possible to choose promising SS when creating ferroelectric materials, including textured piezoelectric ceramic materials for piezoelectric transducers for various purposes: Piezotransformers, piezoelectric motors, ultrasonic emitters, filter devices, ultrasonic flaw detectors, accelerometers, etc.https://www.worldscientific.com/doi/10.1142/S2010135X22440040Solid solutionsmulticomponent systemslead titanate–zirconateelectronegativitydielectric properties |
| spellingShingle | Andryushin Konstantin Dudkina Svetlana Shilkina Lidiya Sahoo Sushrisangita Moysa Maksim Andryushina Inna Verbenko Iliya Reznichenko Larisa Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations Journal of Advanced Dielectrics Solid solutions multicomponent systems lead titanate–zirconate electronegativity dielectric properties |
| title | Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| title_full | Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| title_fullStr | Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| title_full_unstemmed | Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| title_short | Peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| title_sort | peculiarities of the dependences of the dielectric properties of solid solutions of multicomponent systems on the electronegativity of their constituent cations |
| topic | Solid solutions multicomponent systems lead titanate–zirconate electronegativity dielectric properties |
| url | https://www.worldscientific.com/doi/10.1142/S2010135X22440040 |
| work_keys_str_mv | AT andryushinkonstantin peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT dudkinasvetlana peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT shilkinalidiya peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT sahoosushrisangita peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT moysamaksim peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT andryushinainna peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT verbenkoiliya peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations AT reznichenkolarisa peculiaritiesofthedependencesofthedielectricpropertiesofsolidsolutionsofmulticomponentsystemsontheelectronegativityoftheirconstituentcations |