Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids
SRN1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with water to remove alka...
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-04-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/17/5/4782/ |
| _version_ | 1818303335202029568 |
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| author | Seiichi Toyoshima Akio Kamimura |
| author_facet | Seiichi Toyoshima Akio Kamimura |
| author_sort | Seiichi Toyoshima |
| collection | DOAJ |
| description | SRN1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with water to remove alkali metallic salts. The reaction rate is slower than the corresponding SRN1 reaction in DMSO, but no acceleration on irradiation or no inhibition in the presence of m-DNB are observed. |
| first_indexed | 2024-12-13T05:53:10Z |
| format | Article |
| id | doaj.art-9c12db77893a4ee98f1f0735f2e0c0fe |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T05:53:10Z |
| publishDate | 2012-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-9c12db77893a4ee98f1f0735f2e0c0fe2022-12-21T23:57:29ZengMDPI AGMolecules1420-30492012-04-0117547824790Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic LiquidsSeiichi ToyoshimaAkio KamimuraSRN1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with water to remove alkali metallic salts. The reaction rate is slower than the corresponding SRN1 reaction in DMSO, but no acceleration on irradiation or no inhibition in the presence of m-DNB are observed.http://www.mdpi.com/1420-3049/17/5/4782/SRN1-type adductsionic liquidsnitro compoundskinetics |
| spellingShingle | Seiichi Toyoshima Akio Kamimura Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids Molecules SRN1-type adducts ionic liquids nitro compounds kinetics |
| title | Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids |
| title_full | Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids |
| title_fullStr | Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids |
| title_full_unstemmed | Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids |
| title_short | Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids |
| title_sort | preparation of srn1 type coupling adducts from aliphatic gem dinitro compounds in ionic liquids |
| topic | SRN1-type adducts ionic liquids nitro compounds kinetics |
| url | http://www.mdpi.com/1420-3049/17/5/4782/ |
| work_keys_str_mv | AT seiichitoyoshima preparationofsrn1typecouplingadductsfromaliphaticgemdinitrocompoundsinionicliquids AT akiokamimura preparationofsrn1typecouplingadductsfromaliphaticgemdinitrocompoundsinionicliquids |