Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands
The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimet...
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| Format: | Article |
| Language: | English |
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MDPI AG
2000-03-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/5/3/439/ |
| _version_ | 1811343361517289472 |
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| author | V. Dodero L. C. Koll J. C. Podestá |
| author_facet | V. Dodero L. C. Koll J. C. Podestá |
| author_sort | V. Dodero |
| collection | DOAJ |
| description | The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions. |
| first_indexed | 2024-04-13T19:28:01Z |
| format | Article |
| id | doaj.art-9c1313b26ade4242a11cd275e23e8af9 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-13T19:28:01Z |
| publishDate | 2000-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-9c1313b26ade4242a11cd275e23e8af92022-12-22T02:33:18ZengMDPI AGMolecules1420-30492000-03-015343944010.3390/50300439Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic LigandsV. DoderoL. C. KollJ. C. PodestáThe syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions.http://www.mdpi.com/1420-3049/5/3/439/tin hydridevinylstannanesadditionstereoselectivitysubstitution |
| spellingShingle | V. Dodero L. C. Koll J. C. Podestá Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands Molecules tin hydride vinylstannanes addition stereoselectivity substitution |
| title | Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands |
| title_full | Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands |
| title_fullStr | Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands |
| title_full_unstemmed | Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands |
| title_short | Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands |
| title_sort | synthesis of ethylenic and acetylenic triorganotins with bulky organic ligands |
| topic | tin hydride vinylstannanes addition stereoselectivity substitution |
| url | http://www.mdpi.com/1420-3049/5/3/439/ |
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