Bis(2-aminopyrimidine-κN1)aqua(nitrato-κO)(nitrato-κ2O,O′)zinc(II)
The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)2(C4H5N3)2(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810036731 |
| Summary: | The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)2(C4H5N3)2(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N—H...O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O—H...O, O—H...N and N—H...O hydrogen bonds into a layer motif parallel to (001). |
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| ISSN: | 1600-5368 |