Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)]
The asymmetric unit of the title compound, [Hg2Br4(C12H12N2)2], contains one half-molecule. The HgII atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808032510 |
| _version_ | 1818941325924368384 |
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| author | Amin Ebadi Roya Ahmadi Vahid Amani Hamid Reza Khavasi Khadijeh Kalateh |
| author_facet | Amin Ebadi Roya Ahmadi Vahid Amani Hamid Reza Khavasi Khadijeh Kalateh |
| author_sort | Amin Ebadi |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Hg2Br4(C12H12N2)2], contains one half-molecule. The HgII atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal Br atom, leading to a centrosymmetric dimeric molecule. There is a π–π contact between the pyridine rings [centroid-to-centroid distance = 3.756 (5) Å]. |
| first_indexed | 2024-12-20T06:53:45Z |
| format | Article |
| id | doaj.art-9c1bc32bd492403cb57fbeed53aca744 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T06:53:45Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9c1bc32bd492403cb57fbeed53aca7442022-12-21T19:49:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1397m139810.1107/S1600536808032510Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)]Amin EbadiRoya AhmadiVahid AmaniHamid Reza KhavasiKhadijeh KalatehThe asymmetric unit of the title compound, [Hg2Br4(C12H12N2)2], contains one half-molecule. The HgII atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal Br atom, leading to a centrosymmetric dimeric molecule. There is a π–π contact between the pyridine rings [centroid-to-centroid distance = 3.756 (5) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808032510 |
| spellingShingle | Amin Ebadi Roya Ahmadi Vahid Amani Hamid Reza Khavasi Khadijeh Kalateh Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] Acta Crystallographica Section E |
| title | Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] |
| title_full | Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] |
| title_fullStr | Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] |
| title_full_unstemmed | Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] |
| title_short | Di-μ-bromido-bis[bromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)mercury(II)] |
| title_sort | di 956 bromido bis bromido 4 4 8242 dimethyl 2 2 8242 bipyridine 954 2n n 8242 mercury ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808032510 |
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