Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V)
In the title compound, [Tb(C10H8N2O2)4(H2O)4][W(CN)8], both metal atoms are eight-coordinated. The TbIII ion displays a dodecahedral geometry, while the Wv ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812005004 |
| _version_ | 1831691731697926144 |
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| author | Ying-Ying Chen Ai-Hua Yuan Mao-Qian Ran Yu-Sheng Shi |
| author_facet | Ying-Ying Chen Ai-Hua Yuan Mao-Qian Ran Yu-Sheng Shi |
| author_sort | Ying-Ying Chen |
| collection | DOAJ |
| description | In the title compound, [Tb(C10H8N2O2)4(H2O)4][W(CN)8], both metal atoms are eight-coordinated. The TbIII ion displays a dodecahedral geometry, while the Wv ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O—H...O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound [Qian & Yuan (2011). Acta Cryst. E67, m845]. |
| first_indexed | 2024-12-20T11:35:58Z |
| format | Article |
| id | doaj.art-9c3e8a8655ec49559762c61933fee4f9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:35:58Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9c3e8a8655ec49559762c61933fee4f92022-12-21T19:42:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m288m28810.1107/S1600536812005004Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V)Ying-Ying ChenAi-Hua YuanMao-Qian RanYu-Sheng ShiIn the title compound, [Tb(C10H8N2O2)4(H2O)4][W(CN)8], both metal atoms are eight-coordinated. The TbIII ion displays a dodecahedral geometry, while the Wv ion exhibits a distorted square-antiprismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O—H...O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound [Qian & Yuan (2011). Acta Cryst. E67, m845].http://scripts.iucr.org/cgi-bin/paper?S1600536812005004 |
| spellingShingle | Ying-Ying Chen Ai-Hua Yuan Mao-Qian Ran Yu-Sheng Shi Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) Acta Crystallographica Section E |
| title | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_full | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_fullStr | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_full_unstemmed | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_short | Tetraaquatetrakis(4,4′-bipyridine dioxide-κO)terbium(III) octacyanidotungstate(V) |
| title_sort | tetraaquatetrakis 4 4 amp 8242 bipyridine dioxide amp 954 o terbium iii octacyanidotungstate v |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812005004 |
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