A statistical proxy for sulphuric acid concentration
Gaseous sulphuric acid is a key precursor for new particle formation in the atmosphere. Previous experimental studies have confirmed a strong correlation between the number concentrations of freshly formed particles and the ambient concentrations of sulphuric acid. This study evaluates a body of exp...
Main Authors: | , , , , , , , , , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Copernicus Publications
2011-11-01
|
Series: | Atmospheric Chemistry and Physics |
Online Access: | http://www.atmos-chem-phys.net/11/11319/2011/acp-11-11319-2011.pdf |
_version_ | 1811278127284879360 |
---|---|
author | S. Mikkonen S. Romakkaniemi J. N. Smith H. Korhonen T. Petäjä C. Plass-Duelmer M. Boy P. H. McMurry K. E. J. Lehtinen J. Joutsensaari A. Hamed R. L. Mauldin III W. Birmili G. Spindler F. Arnold M. Kulmala A. Laaksonen |
author_facet | S. Mikkonen S. Romakkaniemi J. N. Smith H. Korhonen T. Petäjä C. Plass-Duelmer M. Boy P. H. McMurry K. E. J. Lehtinen J. Joutsensaari A. Hamed R. L. Mauldin III W. Birmili G. Spindler F. Arnold M. Kulmala A. Laaksonen |
author_sort | S. Mikkonen |
collection | DOAJ |
description | Gaseous sulphuric acid is a key precursor for new particle formation in the atmosphere. Previous experimental studies have confirmed a strong correlation between the number concentrations of freshly formed particles and the ambient concentrations of sulphuric acid. This study evaluates a body of experimental gas phase sulphuric acid concentrations, as measured by Chemical Ionization Mass Spectrometry (CIMS) during six intensive measurement campaigns and one long-term observational period. The campaign datasets were measured in Hyytiälä, Finland, in 2003 and 2007, in San Pietro Capofiume, Italy, in 2009, in Melpitz, Germany, in 2008, in Atlanta, Georgia, USA, in 2002, and in Niwot Ridge, Colorado, USA, in 2007. The long term data were obtained in Hohenpeissenberg, Germany, during 1998 to 2000. The measured time series were used to construct proximity measures ("proxies") for sulphuric acid concentration by using statistical analysis methods. The objective of this study is to find a proxy for sulfuric acid that is valid in as many different atmospheric environments as possible. Our most accurate and universal formulation of the sulphuric acid concentration proxy uses global solar radiation, SO<sub>2</sub> concentration, condensation sink and relative humidity as predictor variables, yielding a correlation measure (<i>R</i>) of 0.87 between observed concentration and the proxy predictions. Interestingly, the role of the condensation sink in the proxy was only minor, since similarly accurate proxies could be constructed with global solar radiation and SO<sub>2</sub> concentration alone. This could be attributed to SO<sub>2</sub> being an indicator for anthropogenic pollution, including particulate and gaseous emissions which represent sinks for the OH radical that, in turn, is needed for the formation of sulphuric acid. |
first_indexed | 2024-04-13T00:30:14Z |
format | Article |
id | doaj.art-9c5e8432083748aea11354f73193a0de |
institution | Directory Open Access Journal |
issn | 1680-7316 1680-7324 |
language | English |
last_indexed | 2024-04-13T00:30:14Z |
publishDate | 2011-11-01 |
publisher | Copernicus Publications |
record_format | Article |
series | Atmospheric Chemistry and Physics |
spelling | doaj.art-9c5e8432083748aea11354f73193a0de2022-12-22T03:10:30ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242011-11-011121113191133410.5194/acp-11-11319-2011A statistical proxy for sulphuric acid concentrationS. MikkonenS. RomakkaniemiJ. N. SmithH. KorhonenT. PetäjäC. Plass-DuelmerM. BoyP. H. McMurryK. E. J. LehtinenJ. JoutsensaariA. HamedR. L. Mauldin IIIW. BirmiliG. SpindlerF. ArnoldM. KulmalaA. LaaksonenGaseous sulphuric acid is a key precursor for new particle formation in the atmosphere. Previous experimental studies have confirmed a strong correlation between the number concentrations of freshly formed particles and the ambient concentrations of sulphuric acid. This study evaluates a body of experimental gas phase sulphuric acid concentrations, as measured by Chemical Ionization Mass Spectrometry (CIMS) during six intensive measurement campaigns and one long-term observational period. The campaign datasets were measured in Hyytiälä, Finland, in 2003 and 2007, in San Pietro Capofiume, Italy, in 2009, in Melpitz, Germany, in 2008, in Atlanta, Georgia, USA, in 2002, and in Niwot Ridge, Colorado, USA, in 2007. The long term data were obtained in Hohenpeissenberg, Germany, during 1998 to 2000. The measured time series were used to construct proximity measures ("proxies") for sulphuric acid concentration by using statistical analysis methods. The objective of this study is to find a proxy for sulfuric acid that is valid in as many different atmospheric environments as possible. Our most accurate and universal formulation of the sulphuric acid concentration proxy uses global solar radiation, SO<sub>2</sub> concentration, condensation sink and relative humidity as predictor variables, yielding a correlation measure (<i>R</i>) of 0.87 between observed concentration and the proxy predictions. Interestingly, the role of the condensation sink in the proxy was only minor, since similarly accurate proxies could be constructed with global solar radiation and SO<sub>2</sub> concentration alone. This could be attributed to SO<sub>2</sub> being an indicator for anthropogenic pollution, including particulate and gaseous emissions which represent sinks for the OH radical that, in turn, is needed for the formation of sulphuric acid.http://www.atmos-chem-phys.net/11/11319/2011/acp-11-11319-2011.pdf |
spellingShingle | S. Mikkonen S. Romakkaniemi J. N. Smith H. Korhonen T. Petäjä C. Plass-Duelmer M. Boy P. H. McMurry K. E. J. Lehtinen J. Joutsensaari A. Hamed R. L. Mauldin III W. Birmili G. Spindler F. Arnold M. Kulmala A. Laaksonen A statistical proxy for sulphuric acid concentration Atmospheric Chemistry and Physics |
title | A statistical proxy for sulphuric acid concentration |
title_full | A statistical proxy for sulphuric acid concentration |
title_fullStr | A statistical proxy for sulphuric acid concentration |
title_full_unstemmed | A statistical proxy for sulphuric acid concentration |
title_short | A statistical proxy for sulphuric acid concentration |
title_sort | statistical proxy for sulphuric acid concentration |
url | http://www.atmos-chem-phys.net/11/11319/2011/acp-11-11319-2011.pdf |
work_keys_str_mv | AT smikkonen astatisticalproxyforsulphuricacidconcentration AT sromakkaniemi astatisticalproxyforsulphuricacidconcentration AT jnsmith astatisticalproxyforsulphuricacidconcentration AT hkorhonen astatisticalproxyforsulphuricacidconcentration AT tpetaja astatisticalproxyforsulphuricacidconcentration AT cplassduelmer astatisticalproxyforsulphuricacidconcentration AT mboy astatisticalproxyforsulphuricacidconcentration AT phmcmurry astatisticalproxyforsulphuricacidconcentration AT kejlehtinen astatisticalproxyforsulphuricacidconcentration AT jjoutsensaari astatisticalproxyforsulphuricacidconcentration AT ahamed astatisticalproxyforsulphuricacidconcentration AT rlmauldiniii astatisticalproxyforsulphuricacidconcentration AT wbirmili astatisticalproxyforsulphuricacidconcentration AT gspindler astatisticalproxyforsulphuricacidconcentration AT farnold astatisticalproxyforsulphuricacidconcentration AT mkulmala astatisticalproxyforsulphuricacidconcentration AT alaaksonen astatisticalproxyforsulphuricacidconcentration AT smikkonen statisticalproxyforsulphuricacidconcentration AT sromakkaniemi statisticalproxyforsulphuricacidconcentration AT jnsmith statisticalproxyforsulphuricacidconcentration AT hkorhonen statisticalproxyforsulphuricacidconcentration AT tpetaja statisticalproxyforsulphuricacidconcentration AT cplassduelmer statisticalproxyforsulphuricacidconcentration AT mboy statisticalproxyforsulphuricacidconcentration AT phmcmurry statisticalproxyforsulphuricacidconcentration AT kejlehtinen statisticalproxyforsulphuricacidconcentration AT jjoutsensaari statisticalproxyforsulphuricacidconcentration AT ahamed statisticalproxyforsulphuricacidconcentration AT rlmauldiniii statisticalproxyforsulphuricacidconcentration AT wbirmili statisticalproxyforsulphuricacidconcentration AT gspindler statisticalproxyforsulphuricacidconcentration AT farnold statisticalproxyforsulphuricacidconcentration AT mkulmala statisticalproxyforsulphuricacidconcentration AT alaaksonen statisticalproxyforsulphuricacidconcentration |