Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones
Carbon capture and storage (CCS) and carbon capture and utilization (CCU) are two kinds of strategies to reduce the CO<sub>2</sub> concentration in the atmosphere, which is emitted from the burning of fossil fuels and leads to the greenhouse effect. With the unique properties of ionic li...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/3/1024 |
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| author | Ruina Zhang Daqing Hu Ying Zhou Chunliang Ge Huayan Liu Wenyang Fan Lai Li Biao Chen Yepin Cheng Yaoji Chen Wei Zhang Guokai Cui Hanfeng Lu |
| author_facet | Ruina Zhang Daqing Hu Ying Zhou Chunliang Ge Huayan Liu Wenyang Fan Lai Li Biao Chen Yepin Cheng Yaoji Chen Wei Zhang Guokai Cui Hanfeng Lu |
| author_sort | Ruina Zhang |
| collection | DOAJ |
| description | Carbon capture and storage (CCS) and carbon capture and utilization (CCU) are two kinds of strategies to reduce the CO<sub>2</sub> concentration in the atmosphere, which is emitted from the burning of fossil fuels and leads to the greenhouse effect. With the unique properties of ionic liquids (ILs), such as low vapor pressures, tunable structures, high solubilities, and high thermal and chemical stabilities, they could be used as solvents and catalysts for CO<sub>2</sub> capture and conversion into value-added chemicals. In this critical review, we mainly focus our attention on the tuning IL-based catalysts for CO<sub>2</sub> conversion into quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones from <i>o</i>-aminobenzonitriles during this decade (2012~2022). Due to the importance of basicity and nucleophilicity of catalysts, kinds of ILs with basic anions such as [OH], carboxylates, aprotic heterocyclic anions, etc., for conversion CO<sub>2</sub> and <i>o</i>-aminobenzonitriles into quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones via different catalytic mechanisms, including amino preferential activation, CO<sub>2</sub> preferential activation, and simultaneous amino and CO<sub>2</sub> activation, are investigated systematically. Finally, future directions and prospects for CO<sub>2</sub> conversion by IL-based catalysts are outlined. This review is benefit for academic researchers to obtain an overall understanding of the synthesis of quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones from CO<sub>2</sub> and <i>o</i>-aminobenzonitriles by IL-based catalysts. This work will also open a door to develop novel IL-based catalysts for the conversion of other acid gases such as SO<sub>2</sub> and H<sub>2</sub>S. |
| first_indexed | 2024-03-11T09:33:34Z |
| format | Article |
| id | doaj.art-9c854b15769140f9a51a3915594f32e4 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T09:33:34Z |
| publishDate | 2023-01-01 |
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| record_format | Article |
| series | Molecules |
| spelling | doaj.art-9c854b15769140f9a51a3915594f32e42023-11-16T17:26:35ZengMDPI AGMolecules1420-30492023-01-01283102410.3390/molecules28031024Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-dionesRuina Zhang0Daqing Hu1Ying Zhou2Chunliang Ge3Huayan Liu4Wenyang Fan5Lai Li6Biao Chen7Yepin Cheng8Yaoji Chen9Wei Zhang10Guokai Cui11Hanfeng Lu12Innovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaZhejiang Tiandi Environmental Protection Technology Co., Ltd., Hangzhou 310012, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaInnovation Team of Air Pollution Control, Institute of Catalytic Reaction Engineering, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCarbon capture and storage (CCS) and carbon capture and utilization (CCU) are two kinds of strategies to reduce the CO<sub>2</sub> concentration in the atmosphere, which is emitted from the burning of fossil fuels and leads to the greenhouse effect. With the unique properties of ionic liquids (ILs), such as low vapor pressures, tunable structures, high solubilities, and high thermal and chemical stabilities, they could be used as solvents and catalysts for CO<sub>2</sub> capture and conversion into value-added chemicals. In this critical review, we mainly focus our attention on the tuning IL-based catalysts for CO<sub>2</sub> conversion into quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones from <i>o</i>-aminobenzonitriles during this decade (2012~2022). Due to the importance of basicity and nucleophilicity of catalysts, kinds of ILs with basic anions such as [OH], carboxylates, aprotic heterocyclic anions, etc., for conversion CO<sub>2</sub> and <i>o</i>-aminobenzonitriles into quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones via different catalytic mechanisms, including amino preferential activation, CO<sub>2</sub> preferential activation, and simultaneous amino and CO<sub>2</sub> activation, are investigated systematically. Finally, future directions and prospects for CO<sub>2</sub> conversion by IL-based catalysts are outlined. This review is benefit for academic researchers to obtain an overall understanding of the synthesis of quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones from CO<sub>2</sub> and <i>o</i>-aminobenzonitriles by IL-based catalysts. This work will also open a door to develop novel IL-based catalysts for the conversion of other acid gases such as SO<sub>2</sub> and H<sub>2</sub>S.https://www.mdpi.com/1420-3049/28/3/1024aminobenzonitrileCO<sub>2</sub> fixationCO<sub>2</sub> utilizationC1 chemistryCO<sub>2</sub> chemistryCO<sub>2</sub>-philic |
| spellingShingle | Ruina Zhang Daqing Hu Ying Zhou Chunliang Ge Huayan Liu Wenyang Fan Lai Li Biao Chen Yepin Cheng Yaoji Chen Wei Zhang Guokai Cui Hanfeng Lu Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones Molecules aminobenzonitrile CO<sub>2</sub> fixation CO<sub>2</sub> utilization C1 chemistry CO<sub>2</sub> chemistry CO<sub>2</sub>-philic |
| title | Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones |
| title_full | Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones |
| title_fullStr | Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones |
| title_full_unstemmed | Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones |
| title_short | Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones |
| title_sort | tuning ionic liquid based catalysts for co sub 2 sub conversion into quinazoline 2 4 1 i h i 3 i h i diones |
| topic | aminobenzonitrile CO<sub>2</sub> fixation CO<sub>2</sub> utilization C1 chemistry CO<sub>2</sub> chemistry CO<sub>2</sub>-philic |
| url | https://www.mdpi.com/1420-3049/28/3/1024 |
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