(7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate
In the title compound, C18H14NSe+·HSO4−, the cyclopentene ring in the cation has an envelope conformation while the central six-membered 1,4-selenazine ring adopts a sofa conformation. The dihedral angle between the planes of the terminal benzene rings is 68.08&#81...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811047167 |
| _version_ | 1818321965666009088 |
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| author | Gunay Z. Mammadova Zhanna V. Matsulevich Galina N. Borisova Alexander V. Borisov Victor N. Khrustalev |
| author_facet | Gunay Z. Mammadova Zhanna V. Matsulevich Galina N. Borisova Alexander V. Borisov Victor N. Khrustalev |
| author_sort | Gunay Z. Mammadova |
| collection | DOAJ |
| description | In the title compound, C18H14NSe+·HSO4−, the cyclopentene ring in the cation has an envelope conformation while the central six-membered 1,4-selenazine ring adopts a sofa conformation. The dihedral angle between the planes of the terminal benzene rings is 68.08 (11)°. In the crystal, the anions form chains along the c axis through O—H...O hydrogen bonds. Weak C—H...O and C—H...π hydrogen bonds, as well as attractive Se...Se [3.5608 (8) Å] interactions, further consolidate the crystal structure. |
| first_indexed | 2024-12-13T10:49:17Z |
| format | Article |
| id | doaj.art-9c8e3367ea2b49749f162dd7f0474cbe |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:49:17Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9c8e3367ea2b49749f162dd7f0474cbe2022-12-21T23:49:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3286o328710.1107/S1600536811047167(7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfateGunay Z. MammadovaZhanna V. MatsulevichGalina N. BorisovaAlexander V. BorisovVictor N. KhrustalevIn the title compound, C18H14NSe+·HSO4−, the cyclopentene ring in the cation has an envelope conformation while the central six-membered 1,4-selenazine ring adopts a sofa conformation. The dihedral angle between the planes of the terminal benzene rings is 68.08 (11)°. In the crystal, the anions form chains along the c axis through O—H...O hydrogen bonds. Weak C—H...O and C—H...π hydrogen bonds, as well as attractive Se...Se [3.5608 (8) Å] interactions, further consolidate the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811047167 |
| spellingShingle | Gunay Z. Mammadova Zhanna V. Matsulevich Galina N. Borisova Alexander V. Borisov Victor N. Khrustalev (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate Acta Crystallographica Section E |
| title | (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate |
| title_full | (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate |
| title_fullStr | (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate |
| title_full_unstemmed | (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate |
| title_short | (7aR*,12bS*)-8,12b-Dihydro-7aH-indeno[1′,2′:5,6][1,4]selenazino[2,3,4-ij]quinolin-13-ium hydrogen sulfate |
| title_sort | 7ar 12bs 8 12b dihydro 7ah indeno 1 amp 8242 2 amp 8242 5 6 1 4 selenazino 2 3 4 ij quinolin 13 ium hydrogen sulfate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811047167 |
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