Comprehensive review on zinc‐ion battery anode: Challenges and strategies

Abstract Zinc‐ion batteries (ZIBs) have been extensively investigated and discussed as promising energy storage devices in recent years owing to their low cost, high energy density, inherent safety, and low environmental impact. Nevertheless, several challenges remain that need to be prioritized bef...

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Main Authors: Xin Zhang, Jun‐Ping Hu, Na Fu, Wei‐Bin Zhou, Bin Liu, Qi Deng, Xiong‐Wei Wu
Format: Article
Language:English
Published: Wiley 2022-07-01
Series:InfoMat
Subjects:
Online Access:https://doi.org/10.1002/inf2.12306
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author Xin Zhang
Jun‐Ping Hu
Na Fu
Wei‐Bin Zhou
Bin Liu
Qi Deng
Xiong‐Wei Wu
author_facet Xin Zhang
Jun‐Ping Hu
Na Fu
Wei‐Bin Zhou
Bin Liu
Qi Deng
Xiong‐Wei Wu
author_sort Xin Zhang
collection DOAJ
description Abstract Zinc‐ion batteries (ZIBs) have been extensively investigated and discussed as promising energy storage devices in recent years owing to their low cost, high energy density, inherent safety, and low environmental impact. Nevertheless, several challenges remain that need to be prioritized before realizing the widespread application of ZIBs. In particular, the development of zinc anodes has been hindered by many challenges, such as inevitable zinc dendrites, corrosion passivation, and the hydrogen evolution reaction (HER), which have severely limited the practical application of high‐performance ZIBs. This review starts with a systematic discussion of the origins of zinc dendrites, corrosion passivation, and the HER, as well as their effects on battery performance. Subsequently, we discuss solutions to the above problems to protect the zinc anode, including the improvement of zinc anode materials, modification of the anode–electrolyte interface, and optimization of the electrolyte. In particular, this review emphasizes design strategies to protect zinc anodes from an integrated perspective with broad interest rather than a view with limited focus. In the final section, comments and perspectives are provided for the future design of high‐performance zinc anodes.
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spelling doaj.art-9cb07ab767bc43f59646b980f5e7f0322022-12-22T02:59:35ZengWileyInfoMat2567-31652022-07-0147n/an/a10.1002/inf2.12306Comprehensive review on zinc‐ion battery anode: Challenges and strategiesXin Zhang0Jun‐Ping Hu1Na Fu2Wei‐Bin Zhou3Bin Liu4Qi Deng5Xiong‐Wei Wu6State Key Laboratory for Powder Metallurgy Central South University Changsha ChinaSchool of Chemistry and Materials Science Hunan Agricultural University Changsha Hunan ChinaSchool of Chemistry and Materials Science Hunan Agricultural University Changsha Hunan ChinaState Key Laboratory of Utilization of Woody Oil Resource of China, Hunan Provincial Key Laboratory of Oils & Fats Molecular Structure and Function Hunan Academy of Forestry Changsha Hunan ChinaState Key Laboratory for Powder Metallurgy Central South University Changsha ChinaState Key Laboratory of Utilization of Woody Oil Resource of China, Hunan Provincial Key Laboratory of Oils & Fats Molecular Structure and Function Hunan Academy of Forestry Changsha Hunan ChinaSchool of Chemistry and Materials Science Hunan Agricultural University Changsha Hunan ChinaAbstract Zinc‐ion batteries (ZIBs) have been extensively investigated and discussed as promising energy storage devices in recent years owing to their low cost, high energy density, inherent safety, and low environmental impact. Nevertheless, several challenges remain that need to be prioritized before realizing the widespread application of ZIBs. In particular, the development of zinc anodes has been hindered by many challenges, such as inevitable zinc dendrites, corrosion passivation, and the hydrogen evolution reaction (HER), which have severely limited the practical application of high‐performance ZIBs. This review starts with a systematic discussion of the origins of zinc dendrites, corrosion passivation, and the HER, as well as their effects on battery performance. Subsequently, we discuss solutions to the above problems to protect the zinc anode, including the improvement of zinc anode materials, modification of the anode–electrolyte interface, and optimization of the electrolyte. In particular, this review emphasizes design strategies to protect zinc anodes from an integrated perspective with broad interest rather than a view with limited focus. In the final section, comments and perspectives are provided for the future design of high‐performance zinc anodes.https://doi.org/10.1002/inf2.12306corrosionhydrogen evolution reactionzinc‐ion batteriesZn anode protectionZn dendrites
spellingShingle Xin Zhang
Jun‐Ping Hu
Na Fu
Wei‐Bin Zhou
Bin Liu
Qi Deng
Xiong‐Wei Wu
Comprehensive review on zinc‐ion battery anode: Challenges and strategies
InfoMat
corrosion
hydrogen evolution reaction
zinc‐ion batteries
Zn anode protection
Zn dendrites
title Comprehensive review on zinc‐ion battery anode: Challenges and strategies
title_full Comprehensive review on zinc‐ion battery anode: Challenges and strategies
title_fullStr Comprehensive review on zinc‐ion battery anode: Challenges and strategies
title_full_unstemmed Comprehensive review on zinc‐ion battery anode: Challenges and strategies
title_short Comprehensive review on zinc‐ion battery anode: Challenges and strategies
title_sort comprehensive review on zinc ion battery anode challenges and strategies
topic corrosion
hydrogen evolution reaction
zinc‐ion batteries
Zn anode protection
Zn dendrites
url https://doi.org/10.1002/inf2.12306
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