Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review

Metals used in industries are exposed to several processes such as acid cleaning, pickling, and descaling, which leads to corrosion. A good measure of corrosion control has been achieved by reducing the metal impurity content, by corrosion inhibition, the use of modification techniques, and the inco...

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Main Authors: Julius U. Ani, I. O. Obi, Kovo G. Akpomie, Samson I. Eze, G. Nwatu
Format: Article
Language:English
Published: Taylor & Francis Group 2022-07-01
Series:Journal of Natural Fibers
Subjects:
Online Access:http://dx.doi.org/10.1080/15440478.2020.1818345
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author Julius U. Ani
I. O. Obi
Kovo G. Akpomie
Samson I. Eze
G. Nwatu
author_facet Julius U. Ani
I. O. Obi
Kovo G. Akpomie
Samson I. Eze
G. Nwatu
author_sort Julius U. Ani
collection DOAJ
description Metals used in industries are exposed to several processes such as acid cleaning, pickling, and descaling, which leads to corrosion. A good measure of corrosion control has been achieved by reducing the metal impurity content, by corrosion inhibition, the use of modification techniques, and the incorporation of alloying elements. However, the use of corrosion inhibitors seems to be the most economical and practical of the methods. Besides, the use of fibrous plant biomass as corrosion inhibitors has become important as a suitable substitute for the toxic chromates, phosphates, and arsenic-based inhibitors. The constituents in the fibrous plant biomass extracts react with the metal ions on a corroding metal surface forming organometallic complexes. The recent introduction of Density Functional Theory (DFT) in the theoretical study of the electronic structures elucidates the adsorption modes and the individual contributions of the plant extracts. The DFT has proven to be a significant contribution to the conventional methods based on gravimetry, gasometry, and electrochemical investigations for studying corrosion inhibition. This review provides insights into the use of fibrous plant extracts as corrosion inhibitors in acid solution as well as the DFT calculations.
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spelling doaj.art-9cb93b6b84864e6e8e6eaa75db9c46de2023-09-20T12:50:20ZengTaylor & Francis GroupJournal of Natural Fibers1544-04781544-046X2022-07-011972391240110.1080/15440478.2020.18183451818345Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-ReviewJulius U. Ani0I. O. Obi1Kovo G. Akpomie2Samson I. Eze3G. Nwatu4University of NigeriaUniversity of NigeriaUniversity of NigeriaUniversity of NigeriaUniversity of NigeriaMetals used in industries are exposed to several processes such as acid cleaning, pickling, and descaling, which leads to corrosion. A good measure of corrosion control has been achieved by reducing the metal impurity content, by corrosion inhibition, the use of modification techniques, and the incorporation of alloying elements. However, the use of corrosion inhibitors seems to be the most economical and practical of the methods. Besides, the use of fibrous plant biomass as corrosion inhibitors has become important as a suitable substitute for the toxic chromates, phosphates, and arsenic-based inhibitors. The constituents in the fibrous plant biomass extracts react with the metal ions on a corroding metal surface forming organometallic complexes. The recent introduction of Density Functional Theory (DFT) in the theoretical study of the electronic structures elucidates the adsorption modes and the individual contributions of the plant extracts. The DFT has proven to be a significant contribution to the conventional methods based on gravimetry, gasometry, and electrochemical investigations for studying corrosion inhibition. This review provides insights into the use of fibrous plant extracts as corrosion inhibitors in acid solution as well as the DFT calculations.http://dx.doi.org/10.1080/15440478.2020.1818345acid mediacorrosioncorrosion inhibitiondensity functional theorymetalsplant biomass extracts
spellingShingle Julius U. Ani
I. O. Obi
Kovo G. Akpomie
Samson I. Eze
G. Nwatu
Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
Journal of Natural Fibers
acid media
corrosion
corrosion inhibition
density functional theory
metals
plant biomass extracts
title Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
title_full Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
title_fullStr Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
title_full_unstemmed Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
title_short Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review
title_sort corrosion inhibition studies of metals in acid media by fibrous plant biomass extracts and density functional theory a mini review
topic acid media
corrosion
corrosion inhibition
density functional theory
metals
plant biomass extracts
url http://dx.doi.org/10.1080/15440478.2020.1818345
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AT kovogakpomie corrosioninhibitionstudiesofmetalsinacidmediabyfibrousplantbiomassextractsanddensityfunctionaltheoryaminireview
AT samsonieze corrosioninhibitionstudiesofmetalsinacidmediabyfibrousplantbiomassextractsanddensityfunctionaltheoryaminireview
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