Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles
Novel multi-stimuli responsive cotton fibers were developed via spray-coating with an acylhydrazone-based polyviologen (AHPV). Polyviologen was prepared by supramolecular condensation polymerization of bipyridinium dialdehyde with a hydroxyl-substituted aryldihydrazide in an acidified aqueous medium...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-09-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535222003938 |
| _version_ | 1818478003098746880 |
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| author | Rami A. Pashameah Hatun H. Alsharief Omaymah Alaysuy Alia A. Alfi Hana M. Abumelha Turki M. Habeebullah Nashwa M. El-Metwaly |
| author_facet | Rami A. Pashameah Hatun H. Alsharief Omaymah Alaysuy Alia A. Alfi Hana M. Abumelha Turki M. Habeebullah Nashwa M. El-Metwaly |
| author_sort | Rami A. Pashameah |
| collection | DOAJ |
| description | Novel multi-stimuli responsive cotton fibers were developed via spray-coating with an acylhydrazone-based polyviologen (AHPV). Polyviologen was prepared by supramolecular condensation polymerization of bipyridinium dialdehyde with a hydroxyl-substituted aryldihydrazide in an acidified aqueous medium. Transparent AHPV/resin nanocomposite film was deposited onto the surface of cotton fabric by well-dispersion of AHPV as a chromogenic substance in a resin binding agent. Increasing the temperature of the AHPV-coated cotton fabric from room temperature to 85 °C reversibly triggered a change in color from pale yellow (437 nm) to green (607 nm), respectively. The transparent layer immobilized onto the white cotton surface transformed into green under ultraviolet source as demonstrated by CIE Lab parameters. The photochromic impacts were explored at various AHPV. In addition, the AHPV-coated cotton immediately displayed a vapochromic activity upon exposure to NH3(g), and then recovered to pale yellow after removing the ammonia source away. The current AHPV-coated cotton fabric displayed a limit of detection (LOD) to NH3(aq) in the range of 50–150 ppm. The spray-coated cotton fabrics demonstrated a reversible photochromism, thermochromism and vapochromism with high stability. The produced AHPV nanoparticles were also studied by transmission electron microscopy (TEM), demonstrating particle diameter of 74–92 nm. The mechanical and morphological properties of the spray-coated cotton fabrics were also explored. The surface morphology of AHPV-finished samples was examined by Fourier-transform infrared (FTIR) and scanning electron microscopy (SEM). No considerable defects were observed in permeability to air and bending length of AHPV-finished samples. Additionally, high colorfastness was monitored for the AHPV-finished cotton substrates. The cytotoxic activity of the AHPV-finished cotton was also examined. Mechanistic study accounting for the multichromic activity of acylhydrazone-based polyviologen is explored. |
| first_indexed | 2024-12-10T09:43:13Z |
| format | Article |
| id | doaj.art-9cd0e5adff6a4fb09c9a7e441a751d60 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-12-10T09:43:13Z |
| publishDate | 2022-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-9cd0e5adff6a4fb09c9a7e441a751d602022-12-22T01:53:55ZengElsevierArabian Journal of Chemistry1878-53522022-09-01159104077Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textilesRami A. Pashameah0Hatun H. Alsharief1Omaymah Alaysuy2Alia A. Alfi3Hana M. Abumelha4Turki M. Habeebullah5Nashwa M. El-Metwaly6Department of Chemistry, Faculty of Applied Science, Umm Al Qura University, Makkah 24230, Saudi ArabiaDepartment of Chemistry, Faculty of Applied Science, Umm Al Qura University, Makkah 24230, Saudi ArabiaDepartment of Chemistry, College of Science, University of Tabuk, 71474 Tabuk, Saudi ArabiaDepartment of Chemistry, Faculty of Applied Science, Umm Al Qura University, Makkah 24230, Saudi ArabiaDepartment of Chemistry ,College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi ArabiaDepartment of Environment and Health Research, Custodian of Two Holy Mosques Institute for Hajj and Umrah Research, Umm Al Qura University, Makkah, Saudi ArabiaDepartment of Chemistry, Faculty of Applied Science, Umm Al Qura University, Makkah 24230, Saudi Arabia; Department of Chemistry, Faculty of Science, Mansoura University, El-Gomhoria Street 35516, Egypt; Corresponding author.Novel multi-stimuli responsive cotton fibers were developed via spray-coating with an acylhydrazone-based polyviologen (AHPV). Polyviologen was prepared by supramolecular condensation polymerization of bipyridinium dialdehyde with a hydroxyl-substituted aryldihydrazide in an acidified aqueous medium. Transparent AHPV/resin nanocomposite film was deposited onto the surface of cotton fabric by well-dispersion of AHPV as a chromogenic substance in a resin binding agent. Increasing the temperature of the AHPV-coated cotton fabric from room temperature to 85 °C reversibly triggered a change in color from pale yellow (437 nm) to green (607 nm), respectively. The transparent layer immobilized onto the white cotton surface transformed into green under ultraviolet source as demonstrated by CIE Lab parameters. The photochromic impacts were explored at various AHPV. In addition, the AHPV-coated cotton immediately displayed a vapochromic activity upon exposure to NH3(g), and then recovered to pale yellow after removing the ammonia source away. The current AHPV-coated cotton fabric displayed a limit of detection (LOD) to NH3(aq) in the range of 50–150 ppm. The spray-coated cotton fabrics demonstrated a reversible photochromism, thermochromism and vapochromism with high stability. The produced AHPV nanoparticles were also studied by transmission electron microscopy (TEM), demonstrating particle diameter of 74–92 nm. The mechanical and morphological properties of the spray-coated cotton fabrics were also explored. The surface morphology of AHPV-finished samples was examined by Fourier-transform infrared (FTIR) and scanning electron microscopy (SEM). No considerable defects were observed in permeability to air and bending length of AHPV-finished samples. Additionally, high colorfastness was monitored for the AHPV-finished cotton substrates. The cytotoxic activity of the AHPV-finished cotton was also examined. Mechanistic study accounting for the multichromic activity of acylhydrazone-based polyviologen is explored.http://www.sciencedirect.com/science/article/pii/S1878535222003938Smart textileAcylhydrazone-based polyviologenTemperature-driven fabricAmmonia sensorPhotochromism |
| spellingShingle | Rami A. Pashameah Hatun H. Alsharief Omaymah Alaysuy Alia A. Alfi Hana M. Abumelha Turki M. Habeebullah Nashwa M. El-Metwaly Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles Arabian Journal of Chemistry Smart textile Acylhydrazone-based polyviologen Temperature-driven fabric Ammonia sensor Photochromism |
| title | Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles |
| title_full | Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles |
| title_fullStr | Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles |
| title_full_unstemmed | Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles |
| title_short | Cotton fabrics treated with acylhydrazone-based polyviologen to create innovative multi-stimulus responsive textiles |
| title_sort | cotton fabrics treated with acylhydrazone based polyviologen to create innovative multi stimulus responsive textiles |
| topic | Smart textile Acylhydrazone-based polyviologen Temperature-driven fabric Ammonia sensor Photochromism |
| url | http://www.sciencedirect.com/science/article/pii/S1878535222003938 |
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