Flexible highly conductive films based on expanded graphite /polymer nanocomposites

Highly electrically and thermally conducting films of expanded graphite/polymer nanocomposites were fabricated using an approach based on solution mixing methods. The use of Hydroxyethylcellulose and benzylic alcohol based solutions provides efficient dispersion and better exfoliation of multilayer...

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Main Authors: Silvia V. G. Nista, Andrei V. Alaferdov, Yuri H. Isayama, Lucia H. I. Mei, Stanislav A. Moshkalev
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-04-01
Series:Frontiers in Nanotechnology
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fnano.2023.1135835/full
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author Silvia V. G. Nista
Andrei V. Alaferdov
Yuri H. Isayama
Lucia H. I. Mei
Stanislav A. Moshkalev
author_facet Silvia V. G. Nista
Andrei V. Alaferdov
Yuri H. Isayama
Lucia H. I. Mei
Stanislav A. Moshkalev
author_sort Silvia V. G. Nista
collection DOAJ
description Highly electrically and thermally conducting films of expanded graphite/polymer nanocomposites were fabricated using an approach based on solution mixing methods. The use of Hydroxyethylcellulose and benzylic alcohol based solutions provides efficient dispersion and better exfoliation of multilayer graphene (nanographite) flakes that are further aligned in extended 2D layers forming continuous conductive pathways during lamination (hot calendering) process. Very high electrical conductivity (190 S/cm) was obtained for fabricated layered films. In contrast, for films produced by a conventional mixing and deposition method with acrylic copolymer and the same nanographitic material, with flakes randomly distributed within the composite, much lower conductivities (2.4 S/cm) were obtained.
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spelling doaj.art-9cd9ded567b34a11aae76ce52148eed52023-04-12T05:19:07ZengFrontiers Media S.A.Frontiers in Nanotechnology2673-30132023-04-01510.3389/fnano.2023.11358351135835Flexible highly conductive films based on expanded graphite /polymer nanocompositesSilvia V. G. Nista0Andrei V. Alaferdov1Yuri H. Isayama2Lucia H. I. Mei3Stanislav A. Moshkalev4Center for Semiconductor Components and Nanotechnology (CCSNano), UNICAMP, Campinas, BrazilEldorado Research Institute, Campinas, BrazilCenter for Semiconductor Components and Nanotechnology (CCSNano), UNICAMP, Campinas, BrazilDepartment of Materials and Bioprocess Engineering (DEMBio), Faculty of Chemical Engineering, UNICAMP, Campinas, BrazilCenter for Semiconductor Components and Nanotechnology (CCSNano), UNICAMP, Campinas, BrazilHighly electrically and thermally conducting films of expanded graphite/polymer nanocomposites were fabricated using an approach based on solution mixing methods. The use of Hydroxyethylcellulose and benzylic alcohol based solutions provides efficient dispersion and better exfoliation of multilayer graphene (nanographite) flakes that are further aligned in extended 2D layers forming continuous conductive pathways during lamination (hot calendering) process. Very high electrical conductivity (190 S/cm) was obtained for fabricated layered films. In contrast, for films produced by a conventional mixing and deposition method with acrylic copolymer and the same nanographitic material, with flakes randomly distributed within the composite, much lower conductivities (2.4 S/cm) were obtained.https://www.frontiersin.org/articles/10.3389/fnano.2023.1135835/fullnanographiteexpanded graphitecompositehydroxyethylcelluloseelectrical and thermal conductivitygraphene
spellingShingle Silvia V. G. Nista
Andrei V. Alaferdov
Yuri H. Isayama
Lucia H. I. Mei
Stanislav A. Moshkalev
Flexible highly conductive films based on expanded graphite /polymer nanocomposites
Frontiers in Nanotechnology
nanographite
expanded graphite
composite
hydroxyethylcellulose
electrical and thermal conductivity
graphene
title Flexible highly conductive films based on expanded graphite /polymer nanocomposites
title_full Flexible highly conductive films based on expanded graphite /polymer nanocomposites
title_fullStr Flexible highly conductive films based on expanded graphite /polymer nanocomposites
title_full_unstemmed Flexible highly conductive films based on expanded graphite /polymer nanocomposites
title_short Flexible highly conductive films based on expanded graphite /polymer nanocomposites
title_sort flexible highly conductive films based on expanded graphite polymer nanocomposites
topic nanographite
expanded graphite
composite
hydroxyethylcellulose
electrical and thermal conductivity
graphene
url https://www.frontiersin.org/articles/10.3389/fnano.2023.1135835/full
work_keys_str_mv AT silviavgnista flexiblehighlyconductivefilmsbasedonexpandedgraphitepolymernanocomposites
AT andreivalaferdov flexiblehighlyconductivefilmsbasedonexpandedgraphitepolymernanocomposites
AT yurihisayama flexiblehighlyconductivefilmsbasedonexpandedgraphitepolymernanocomposites
AT luciahimei flexiblehighlyconductivefilmsbasedonexpandedgraphitepolymernanocomposites
AT stanislavamoshkalev flexiblehighlyconductivefilmsbasedonexpandedgraphitepolymernanocomposites