Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers

We report on the synthesis and magnetic characterization of ultralong (1 cm) arrays of highly ordered coaxial nanowires with nickel cores and graphene stacking shells (also known as metal-filled carbon nanotubes). Carbon-containing nickel nanowires are first grown on a nanograted surface by magnetro...

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Main Authors: Abdel-Aziz El Mel, Jean-Luc Duvail, Eric Gautron, Wei Xu, Chang-Hwan Choi, Benoit Angleraud, Agnès Granier, Pierre-Yves Tessier
Format: Article
Language:English
Published: Beilstein-Institut 2012-12-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.3.95
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author Abdel-Aziz El Mel
Jean-Luc Duvail
Eric Gautron
Wei Xu
Chang-Hwan Choi
Benoit Angleraud
Agnès Granier
Pierre-Yves Tessier
author_facet Abdel-Aziz El Mel
Jean-Luc Duvail
Eric Gautron
Wei Xu
Chang-Hwan Choi
Benoit Angleraud
Agnès Granier
Pierre-Yves Tessier
author_sort Abdel-Aziz El Mel
collection DOAJ
description We report on the synthesis and magnetic characterization of ultralong (1 cm) arrays of highly ordered coaxial nanowires with nickel cores and graphene stacking shells (also known as metal-filled carbon nanotubes). Carbon-containing nickel nanowires are first grown on a nanograted surface by magnetron sputtering. Then, a post-annealing treatment favors the metal-catalyzed crystallization of carbon into stacked graphene layers rolled around the nickel cores. The observed uniaxial magnetic anisotropy field oriented along the nanowire axis is an indication that the shape anisotropy dominates the dipolar coupling between the wires. We further show that the thermal treatment induces a decrease in the coercivity of the nanowire arrays. This reflects an enhancement of the quality of the nickel nanowires after annealing attributed to a decrease of the roughness of the nickel surface and to a reduction of the defect density. This new type of graphene–ferromagnetic-metal nanowire appears to be an interesting building block for spintronic applications.
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spelling doaj.art-9ce286a371c3425ea050a125ecfb5a1b2022-12-21T23:54:15ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862012-12-013184685110.3762/bjnano.3.952190-4286-3-95Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layersAbdel-Aziz El Mel0Jean-Luc Duvail1Eric Gautron2Wei Xu3Chang-Hwan Choi4Benoit Angleraud5Agnès Granier6Pierre-Yves Tessier7Institut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959Institut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959Institut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959Department of Mechanical Engineering, Stevens Institute of Technology, Hoboken, NJ 07030, USADepartment of Mechanical Engineering, Stevens Institute of Technology, Hoboken, NJ 07030, USAInstitut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959Institut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959Institut des Matériaux Jean Rouxel, IMN, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes cedex 3, France, Telephone: +33 (0) 240 376 434, Fax: +33 (0) 240 373 959We report on the synthesis and magnetic characterization of ultralong (1 cm) arrays of highly ordered coaxial nanowires with nickel cores and graphene stacking shells (also known as metal-filled carbon nanotubes). Carbon-containing nickel nanowires are first grown on a nanograted surface by magnetron sputtering. Then, a post-annealing treatment favors the metal-catalyzed crystallization of carbon into stacked graphene layers rolled around the nickel cores. The observed uniaxial magnetic anisotropy field oriented along the nanowire axis is an indication that the shape anisotropy dominates the dipolar coupling between the wires. We further show that the thermal treatment induces a decrease in the coercivity of the nanowire arrays. This reflects an enhancement of the quality of the nickel nanowires after annealing attributed to a decrease of the roughness of the nickel surface and to a reduction of the defect density. This new type of graphene–ferromagnetic-metal nanowire appears to be an interesting building block for spintronic applications.https://doi.org/10.3762/bjnano.3.95carbonferromagneticgraphenenanofabricationnanowiresnickelphase separation
spellingShingle Abdel-Aziz El Mel
Jean-Luc Duvail
Eric Gautron
Wei Xu
Chang-Hwan Choi
Benoit Angleraud
Agnès Granier
Pierre-Yves Tessier
Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
Beilstein Journal of Nanotechnology
carbon
ferromagnetic
graphene
nanofabrication
nanowires
nickel
phase separation
title Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
title_full Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
title_fullStr Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
title_full_unstemmed Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
title_short Highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
title_sort highly ordered ultralong magnetic nanowires wrapped in stacked graphene layers
topic carbon
ferromagnetic
graphene
nanofabrication
nanowires
nickel
phase separation
url https://doi.org/10.3762/bjnano.3.95
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