Cold Cathodes with Two-Dimensional van der Waals Materials

Two-dimensional van der Waals materials could be used as electron emitters alone or stacked in a heterostructure. Many significant phenomena of two-dimensional van der Waals field emitters have been observed and predicted since the landmark discovery of graphene. Due to the wide variety of heterostr...

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Main Authors: Yicong Chen, Jun Chen, Zhibing Li
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/17/2437
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author Yicong Chen
Jun Chen
Zhibing Li
author_facet Yicong Chen
Jun Chen
Zhibing Li
author_sort Yicong Chen
collection DOAJ
description Two-dimensional van der Waals materials could be used as electron emitters alone or stacked in a heterostructure. Many significant phenomena of two-dimensional van der Waals field emitters have been observed and predicted since the landmark discovery of graphene. Due to the wide variety of heterostructures that integrate an atomic monolayer or multilayers with insulator nanofilms or metallic cathodes by van der Waals force, the diversity of van der Waals materials is large to be chosen from, which are appealing for further investigation. Until now, increasing the efficiency, stability, and uniformity in electron emission of cold cathodes with two-dimensional materials is still of interest in research. Some novel behaviors in electron emission, such as coherence and directionality, have been revealed by the theoretical study down to the atomic scale and could lead to innovative applications. Although intensive emission in the direction normal to two-dimensional emitters has been observed in experiments, the theoretical mechanism is still incomplete. In this paper, we will review some late progresses related to the cold cathodes with two-dimensional van der Waals materials, both in experiments and in the theoretical study, emphasizing the phenomena which are absent in the conventional cold cathodes. The review will cover the fabrication of several kinds of emitter structures for field emission applications, the state of the art of their field emission properties and the existing field emission model. In the end, some perspectives on their future research trend will also be given.
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spelling doaj.art-9cf4e4c68a6b4f98b159b43773d6d2502023-11-19T08:36:40ZengMDPI AGNanomaterials2079-49912023-08-011317243710.3390/nano13172437Cold Cathodes with Two-Dimensional van der Waals MaterialsYicong Chen0Jun Chen1Zhibing Li2State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technologies, Sun Yat-Sen University, Guangzhou 510275, ChinaState Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technologies, Sun Yat-Sen University, Guangzhou 510275, ChinaState Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Province Key Laboratory of Display Material and Technology, School of Science, Sun Yat-Sen University, Shenzhen 518000, ChinaTwo-dimensional van der Waals materials could be used as electron emitters alone or stacked in a heterostructure. Many significant phenomena of two-dimensional van der Waals field emitters have been observed and predicted since the landmark discovery of graphene. Due to the wide variety of heterostructures that integrate an atomic monolayer or multilayers with insulator nanofilms or metallic cathodes by van der Waals force, the diversity of van der Waals materials is large to be chosen from, which are appealing for further investigation. Until now, increasing the efficiency, stability, and uniformity in electron emission of cold cathodes with two-dimensional materials is still of interest in research. Some novel behaviors in electron emission, such as coherence and directionality, have been revealed by the theoretical study down to the atomic scale and could lead to innovative applications. Although intensive emission in the direction normal to two-dimensional emitters has been observed in experiments, the theoretical mechanism is still incomplete. In this paper, we will review some late progresses related to the cold cathodes with two-dimensional van der Waals materials, both in experiments and in the theoretical study, emphasizing the phenomena which are absent in the conventional cold cathodes. The review will cover the fabrication of several kinds of emitter structures for field emission applications, the state of the art of their field emission properties and the existing field emission model. In the end, some perspectives on their future research trend will also be given.https://www.mdpi.com/2079-4991/13/17/2437cold cathode2D van der Waals materialsfield emissioncoherencehot electron emission
spellingShingle Yicong Chen
Jun Chen
Zhibing Li
Cold Cathodes with Two-Dimensional van der Waals Materials
Nanomaterials
cold cathode
2D van der Waals materials
field emission
coherence
hot electron emission
title Cold Cathodes with Two-Dimensional van der Waals Materials
title_full Cold Cathodes with Two-Dimensional van der Waals Materials
title_fullStr Cold Cathodes with Two-Dimensional van der Waals Materials
title_full_unstemmed Cold Cathodes with Two-Dimensional van der Waals Materials
title_short Cold Cathodes with Two-Dimensional van der Waals Materials
title_sort cold cathodes with two dimensional van der waals materials
topic cold cathode
2D van der Waals materials
field emission
coherence
hot electron emission
url https://www.mdpi.com/2079-4991/13/17/2437
work_keys_str_mv AT yicongchen coldcathodeswithtwodimensionalvanderwaalsmaterials
AT junchen coldcathodeswithtwodimensionalvanderwaalsmaterials
AT zhibingli coldcathodeswithtwodimensionalvanderwaalsmaterials