Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts
This work is devoted to the investigation of the possibility of use of ruthenium-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in hydrogenation of levulinic acid to gamma- valerolactone, which is a semi-product for obtaining of liquid fuel components. Ca...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2016-08-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/3760 |
| Summary: | This work is devoted to the investigation of the possibility of use of ruthenium-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in hydrogenation of levulinic acid to gamma- valerolactone, which is a semi-product for obtaining of liquid fuel components. Catalyst 5 %-Ru/MN100 was shown to allow carrying out the hydrogenation of levulinic acid in aqueous medium with high yields of gamma- valerolactone (higher than 99 %) and it can compete with traditional catalyst 5 %-Ru/C. It is noteworthy that synthesized HPS-based catalyst has high activity, and thus the necessity of addition in reaction mixture of acidic co-catalysts is absent. |
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| ISSN: | 2283-9216 |