Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts
This work is devoted to the investigation of the possibility of use of ruthenium-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in hydrogenation of levulinic acid to gamma- valerolactone, which is a semi-product for obtaining of liquid fuel components. Ca...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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AIDIC Servizi S.r.l.
2016-08-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/3760 |
| _version_ | 1818854256081371136 |
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| author | I.I. Protsenko L.Zh. Nikoshvili V.G. Matveeva E.M. Sulman E. Rebrov |
| author_facet | I.I. Protsenko L.Zh. Nikoshvili V.G. Matveeva E.M. Sulman E. Rebrov |
| author_sort | I.I. Protsenko |
| collection | DOAJ |
| description | This work is devoted to the investigation of the possibility of use of ruthenium-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in hydrogenation of levulinic acid to gamma- valerolactone, which is a semi-product for obtaining of liquid fuel components. Catalyst 5 %-Ru/MN100 was shown to allow carrying out the hydrogenation of levulinic acid in aqueous medium with high yields of gamma- valerolactone (higher than 99 %) and it can compete with traditional catalyst 5 %-Ru/C. It is noteworthy that synthesized HPS-based catalyst has high activity, and thus the necessity of addition in reaction mixture of acidic co-catalysts is absent. |
| first_indexed | 2024-12-19T07:49:49Z |
| format | Article |
| id | doaj.art-9cf8b861f1824b279590ea3826a128ff |
| institution | Directory Open Access Journal |
| issn | 2283-9216 |
| language | English |
| last_indexed | 2024-12-19T07:49:49Z |
| publishDate | 2016-08-01 |
| publisher | AIDIC Servizi S.r.l. |
| record_format | Article |
| series | Chemical Engineering Transactions |
| spelling | doaj.art-9cf8b861f1824b279590ea3826a128ff2022-12-21T20:30:13ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162016-08-015210.3303/CET1652114Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing CatalystsI.I. ProtsenkoL.Zh. NikoshviliV.G. MatveevaE.M. SulmanE. RebrovThis work is devoted to the investigation of the possibility of use of ruthenium-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in hydrogenation of levulinic acid to gamma- valerolactone, which is a semi-product for obtaining of liquid fuel components. Catalyst 5 %-Ru/MN100 was shown to allow carrying out the hydrogenation of levulinic acid in aqueous medium with high yields of gamma- valerolactone (higher than 99 %) and it can compete with traditional catalyst 5 %-Ru/C. It is noteworthy that synthesized HPS-based catalyst has high activity, and thus the necessity of addition in reaction mixture of acidic co-catalysts is absent.https://www.cetjournal.it/index.php/cet/article/view/3760 |
| spellingShingle | I.I. Protsenko L.Zh. Nikoshvili V.G. Matveeva E.M. Sulman E. Rebrov Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts Chemical Engineering Transactions |
| title | Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts |
| title_full | Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts |
| title_fullStr | Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts |
| title_full_unstemmed | Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts |
| title_short | Selective Hydrogenation of Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Ru-Containing Catalysts |
| title_sort | selective hydrogenation of levulinic acid to gamma valerolactone using polymer based ru containing catalysts |
| url | https://www.cetjournal.it/index.php/cet/article/view/3760 |
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