| Summary: | The title compound, C9H12N2OS, was obtained unexpectedly in a multicomponent reaction of an equimolar ratio of phenyl isothiocyanate, malononitrile and aminoethanol. The –C(H2)–N(H)–(C=S)–N(H)– methylthiourea–methane group is almost normal to the phenyl ring, with a dihedral angle of 71.13 (9)°. The N—C—C—O torsion angle is 72.8 (2)°. In the crystal, molecules are connected by N—H...O, O—H...S and N—H...O hydrogen bonds, forming a three-dimensional network.
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