Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility

Raw gas gathered from well production has to be treated to extract its ethane, to remove carbon dioxide (CO2) from it and to dry it, so that the send-out ethane gas complies with transport constraints and meets sales-gas specifications. Two distinct families of solvents are used generically for such...

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Main Authors: Hassan Ghanbarabadi, Behnam Khoshandam, David A. Wood
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2019-03-01
Series:Petroleum
Online Access:http://www.sciencedirect.com/science/article/pii/S2405656117302481
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author Hassan Ghanbarabadi
Behnam Khoshandam
David A. Wood
author_facet Hassan Ghanbarabadi
Behnam Khoshandam
David A. Wood
author_sort Hassan Ghanbarabadi
collection DOAJ
description Raw gas gathered from well production has to be treated to extract its ethane, to remove carbon dioxide (CO2) from it and to dry it, so that the send-out ethane gas complies with transport constraints and meets sales-gas specifications. Two distinct families of solvents are used generically for such gas treatment: chemical and physical solvents. The South Pars gas field development phases 9 and 10 feeds gas and natural gas liquids into a processing and fractionation plant (one of the largest gas processing plants in Iran), and is associated with concentrations of 5.37% mole CO2 in the raw gas produced. Furthermore, there are potential problems associated with the CO2 treatment, such as the high-energy requirements for amine solvent regeneration, corrosion caused by aqueous amine solvents and waste/losses (solubility, vaporization) of the solvent used to remove CO2 in the ethane treatment unit.A feasibility simulation study was conducted to evaluate the utilization of Sulfinol-M + AMP solvent (Sulfolane plus Methyl di-ethanol amine plus 2-amino-2-methyl-1-propanol (AMP) plus H2O) to replace the aqueous amine solvent (DEA) currently used in the ethane treatment unit of South Pars phases 9 and 10 gas processing plant. The simulation of the Sulfinol-M + AMP process demonstrates less energy consumption (11241.242 kw versus 11290.398 kw for DEA), negligible corrosion and lower losses of solvent (376.493 kg/h versus 409.2421 kg/h) relative to alternative solvents considered, because of its low vapor pressure. Keywords: CO2, Solvent, Sulfinol-M+AMP, DEA, MDEA, Amine, Absorption, Simulation, Sulfolane
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spelling doaj.art-9d346bd8f8034b069dcc1549e16b0dc62022-12-21T17:26:21ZengKeAi Communications Co., Ltd.Petroleum2405-65612019-03-015190101Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facilityHassan Ghanbarabadi0Behnam Khoshandam1David A. Wood2Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan, Iran; Department of Chemical Engineering, Technical and Vocational University(TVU), Jajarm Branch, Jajarm, IranFaculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan, Iran; Corresponding author.DWA Energy Limited, Lincoln, United KingdomRaw gas gathered from well production has to be treated to extract its ethane, to remove carbon dioxide (CO2) from it and to dry it, so that the send-out ethane gas complies with transport constraints and meets sales-gas specifications. Two distinct families of solvents are used generically for such gas treatment: chemical and physical solvents. The South Pars gas field development phases 9 and 10 feeds gas and natural gas liquids into a processing and fractionation plant (one of the largest gas processing plants in Iran), and is associated with concentrations of 5.37% mole CO2 in the raw gas produced. Furthermore, there are potential problems associated with the CO2 treatment, such as the high-energy requirements for amine solvent regeneration, corrosion caused by aqueous amine solvents and waste/losses (solubility, vaporization) of the solvent used to remove CO2 in the ethane treatment unit.A feasibility simulation study was conducted to evaluate the utilization of Sulfinol-M + AMP solvent (Sulfolane plus Methyl di-ethanol amine plus 2-amino-2-methyl-1-propanol (AMP) plus H2O) to replace the aqueous amine solvent (DEA) currently used in the ethane treatment unit of South Pars phases 9 and 10 gas processing plant. The simulation of the Sulfinol-M + AMP process demonstrates less energy consumption (11241.242 kw versus 11290.398 kw for DEA), negligible corrosion and lower losses of solvent (376.493 kg/h versus 409.2421 kg/h) relative to alternative solvents considered, because of its low vapor pressure. Keywords: CO2, Solvent, Sulfinol-M+AMP, DEA, MDEA, Amine, Absorption, Simulation, Sulfolanehttp://www.sciencedirect.com/science/article/pii/S2405656117302481
spellingShingle Hassan Ghanbarabadi
Behnam Khoshandam
David A. Wood
Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
Petroleum
title Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
title_full Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
title_fullStr Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
title_full_unstemmed Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
title_short Simulation of CO2 removal from ethane with Sulfinol-M+AMP solvent instead of DEA solvent in the South Pars phases 9 and 10 gas processing facility
title_sort simulation of co2 removal from ethane with sulfinol m amp solvent instead of dea solvent in the south pars phases 9 and 10 gas processing facility
url http://www.sciencedirect.com/science/article/pii/S2405656117302481
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AT behnamkhoshandam simulationofco2removalfromethanewithsulfinolmampsolventinsteadofdeasolventinthesouthparsphases9and10gasprocessingfacility
AT davidawood simulationofco2removalfromethanewithsulfinolmampsolventinsteadofdeasolventinthesouthparsphases9and10gasprocessingfacility