Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent
Abstract Molybdenum disulfide (MoS2) is an extremely intriguing low-D layered material due to its exotic electronic, optical, and mechanical properties, which could be well exploited for numerous applications to energy storage, sensing, and catalysis, etc., provided a sufficiently low number of laye...
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Format: | Article |
Language: | English |
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SpringerOpen
2019-09-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://link.springer.com/article/10.1186/s11671-019-3126-4 |
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author | Xi Tan Wenbin Kang Jingfeng Liu Chuhong Zhang |
author_facet | Xi Tan Wenbin Kang Jingfeng Liu Chuhong Zhang |
author_sort | Xi Tan |
collection | DOAJ |
description | Abstract Molybdenum disulfide (MoS2) is an extremely intriguing low-D layered material due to its exotic electronic, optical, and mechanical properties, which could be well exploited for numerous applications to energy storage, sensing, and catalysis, etc., provided a sufficiently low number of layers is achieved. A facile exfoliation strategy that leads to the production of few-layered MoS2 is proposed wherein the exfoliation efficacy could be synergistically boosted to > 90% by exploiting ultrasound sonication in supercritical CO2 in conjunction with N-methyl-2-pyrrolidone (NMP) as the intercalating solvent, which is superior to general practiced liquid exfoliation methods wherein only the supernatant is collected to avoid the majority of unexfoliated sediments. The facile and fast exfoliation technique suggests an exciting and feasible solution for scalable production of few-layered MoS2 and establishes a platform that contributes to fulfilling the full potential of this versatile two-dimensional material. |
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institution | Directory Open Access Journal |
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language | English |
last_indexed | 2024-03-12T08:43:06Z |
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spelling | doaj.art-9d41ef1ee66848cab2186df6a50495cf2023-09-02T16:39:45ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-09-011411710.1186/s11671-019-3126-4Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex SolventXi Tan0Wenbin Kang1Jingfeng Liu2Chuhong Zhang3State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan UniversityState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan UniversityState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan UniversityState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan UniversityAbstract Molybdenum disulfide (MoS2) is an extremely intriguing low-D layered material due to its exotic electronic, optical, and mechanical properties, which could be well exploited for numerous applications to energy storage, sensing, and catalysis, etc., provided a sufficiently low number of layers is achieved. A facile exfoliation strategy that leads to the production of few-layered MoS2 is proposed wherein the exfoliation efficacy could be synergistically boosted to > 90% by exploiting ultrasound sonication in supercritical CO2 in conjunction with N-methyl-2-pyrrolidone (NMP) as the intercalating solvent, which is superior to general practiced liquid exfoliation methods wherein only the supernatant is collected to avoid the majority of unexfoliated sediments. The facile and fast exfoliation technique suggests an exciting and feasible solution for scalable production of few-layered MoS2 and establishes a platform that contributes to fulfilling the full potential of this versatile two-dimensional material.http://link.springer.com/article/10.1186/s11671-019-3126-4Molybdenum disulfide (MoS2)ExfoliationSupercritical CO2Ultrasound sonication |
spellingShingle | Xi Tan Wenbin Kang Jingfeng Liu Chuhong Zhang Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent Nanoscale Research Letters Molybdenum disulfide (MoS2) Exfoliation Supercritical CO2 Ultrasound sonication |
title | Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent |
title_full | Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent |
title_fullStr | Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent |
title_full_unstemmed | Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent |
title_short | Synergistic Exfoliation of MoS2 by Ultrasound Sonication in a Supercritical Fluid Based Complex Solvent |
title_sort | synergistic exfoliation of mos2 by ultrasound sonication in a supercritical fluid based complex solvent |
topic | Molybdenum disulfide (MoS2) Exfoliation Supercritical CO2 Ultrasound sonication |
url | http://link.springer.com/article/10.1186/s11671-019-3126-4 |
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