Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process

The photochemical decolorization of C.I. Reactive Orange 16 (RO16), a reactive textile azo dye by the UV/H2O2 process using a batch photoreactor with UV lamps emitting at 253.7 nm, was studied. Complete decolorization of 50.0 mg dm-3 initial dye concentration was achieved in less than 6 min under...

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Main Authors: Mitrović Jelena, Radović Miljana, Bojić Danijela, Anđelković Tatjana, Purenović Milovan, Bojić Aleksandar
Format: Article
Language:English
Published: Serbian Chemical Society 2012-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100187M.pdf
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author Mitrović Jelena
Radović Miljana
Bojić Danijela
Anđelković Tatjana
Purenović Milovan
Bojić Aleksandar
author_facet Mitrović Jelena
Radović Miljana
Bojić Danijela
Anđelković Tatjana
Purenović Milovan
Bojić Aleksandar
author_sort Mitrović Jelena
collection DOAJ
description The photochemical decolorization of C.I. Reactive Orange 16 (RO16), a reactive textile azo dye by the UV/H2O2 process using a batch photoreactor with UV lamps emitting at 253.7 nm, was studied. Complete decolorization of 50.0 mg dm-3 initial dye concentration was achieved in less than 6 min under optimal conditions (25 mM initial peroxide concentration, at pH 7.0 and with UV light intensity 1950 μW cm-2). The effect of experimental variables, such as initial pH, initial concentration of H2O2, initial dye concentration, and the intensity of UV light was studied. The highest decolorization rates were performed at peroxide concentration in range from 20 mM up to 40 mM, above which decolorization was inhibited by a scavenging effect of peroxide. The decolorization was more efficient in neutral pHs. The efficiency of the process was improved in lower initial dye concentration and at higher intensity of UV light.
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spelling doaj.art-9d4268810c8f43bb8ed2037d93ddaa912022-12-21T21:09:37ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392012-01-0177446548110.2298/JSC110216187MDecolorization of textile azo dye reactive orange 16 with UV/H2O2 processMitrović JelenaRadović MiljanaBojić DanijelaAnđelković TatjanaPurenović MilovanBojić AleksandarThe photochemical decolorization of C.I. Reactive Orange 16 (RO16), a reactive textile azo dye by the UV/H2O2 process using a batch photoreactor with UV lamps emitting at 253.7 nm, was studied. Complete decolorization of 50.0 mg dm-3 initial dye concentration was achieved in less than 6 min under optimal conditions (25 mM initial peroxide concentration, at pH 7.0 and with UV light intensity 1950 μW cm-2). The effect of experimental variables, such as initial pH, initial concentration of H2O2, initial dye concentration, and the intensity of UV light was studied. The highest decolorization rates were performed at peroxide concentration in range from 20 mM up to 40 mM, above which decolorization was inhibited by a scavenging effect of peroxide. The decolorization was more efficient in neutral pHs. The efficiency of the process was improved in lower initial dye concentration and at higher intensity of UV light.http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100187M.pdfReactive Orange 16UV/H2O2 processdecolorization
spellingShingle Mitrović Jelena
Radović Miljana
Bojić Danijela
Anđelković Tatjana
Purenović Milovan
Bojić Aleksandar
Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
Journal of the Serbian Chemical Society
Reactive Orange 16
UV/H2O2 process
decolorization
title Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
title_full Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
title_fullStr Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
title_full_unstemmed Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
title_short Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process
title_sort decolorization of textile azo dye reactive orange 16 with uv h2o2 process
topic Reactive Orange 16
UV/H2O2 process
decolorization
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100187M.pdf
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AT bojicdanijela decolorizationoftextileazodyereactiveorange16withuvh2o2process
AT anđelkovictatjana decolorizationoftextileazodyereactiveorange16withuvh2o2process
AT purenovicmilovan decolorizationoftextileazodyereactiveorange16withuvh2o2process
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