Pb(II) Adsorption by a Calcium Metal-Organic Framework
Among the water pollution sources, heavy metals are considered the most hazardous because of their high toxicity to human health and their ability to badly damage the kidneys, brain, and nerves, as well as cause birth defects. Based on the promising features of metal-organic frameworks ( MOFs), they...
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MDPI AG
2022-11-01
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Online Access: | https://www.mdpi.com/2673-4583/12/1/74 |
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author | Mina Aghaee Faranak Manteghi |
author_facet | Mina Aghaee Faranak Manteghi |
author_sort | Mina Aghaee |
collection | DOAJ |
description | Among the water pollution sources, heavy metals are considered the most hazardous because of their high toxicity to human health and their ability to badly damage the kidneys, brain, and nerves, as well as cause birth defects. Based on the promising features of metal-organic frameworks ( MOFs), they could act as a favorable candidate in heavy metal removal applications. A calcium-based metal-organic framework was synthesized by the deposition method using benzene-1,2,4,5-tetracarboxylate as a linker. After characterization of the MOF was performed using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) analyses, it was applied to efficient adsorption of Pb(II) pollutant ions. The potential of obtained MOF, [Ca(H<sub>2</sub>btec)·H<sub>2</sub>O]<sub>n</sub>, H<sub>2</sub>btec: benzene-1,2,4,5-tetracarboxylic acid was investigated by adsorbing Pb(II) ions in an aqueous solution, separating the adsorbent using centrifugation, and finally measuring the residual Pb(II) ions using the ICP-AES method. |
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issn | 2673-4583 |
language | English |
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spelling | doaj.art-9d69957abb9746d99bcd3c6155d9973a2023-11-18T09:48:38ZengMDPI AGChemistry Proceedings2673-45832022-11-011217410.3390/ecsoc-26-13723Pb(II) Adsorption by a Calcium Metal-Organic FrameworkMina Aghaee0Faranak Manteghi1Department of Chemistry, Iran University of Science and Technology, Tehran 1684613114, IranDepartment of Chemistry, Iran University of Science and Technology, Tehran 1684613114, IranAmong the water pollution sources, heavy metals are considered the most hazardous because of their high toxicity to human health and their ability to badly damage the kidneys, brain, and nerves, as well as cause birth defects. Based on the promising features of metal-organic frameworks ( MOFs), they could act as a favorable candidate in heavy metal removal applications. A calcium-based metal-organic framework was synthesized by the deposition method using benzene-1,2,4,5-tetracarboxylate as a linker. After characterization of the MOF was performed using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) analyses, it was applied to efficient adsorption of Pb(II) pollutant ions. The potential of obtained MOF, [Ca(H<sub>2</sub>btec)·H<sub>2</sub>O]<sub>n</sub>, H<sub>2</sub>btec: benzene-1,2,4,5-tetracarboxylic acid was investigated by adsorbing Pb(II) ions in an aqueous solution, separating the adsorbent using centrifugation, and finally measuring the residual Pb(II) ions using the ICP-AES method.https://www.mdpi.com/2673-4583/12/1/74metal-organic frameworkgreen synthesisheavy metaladsorption |
spellingShingle | Mina Aghaee Faranak Manteghi Pb(II) Adsorption by a Calcium Metal-Organic Framework Chemistry Proceedings metal-organic framework green synthesis heavy metal adsorption |
title | Pb(II) Adsorption by a Calcium Metal-Organic Framework |
title_full | Pb(II) Adsorption by a Calcium Metal-Organic Framework |
title_fullStr | Pb(II) Adsorption by a Calcium Metal-Organic Framework |
title_full_unstemmed | Pb(II) Adsorption by a Calcium Metal-Organic Framework |
title_short | Pb(II) Adsorption by a Calcium Metal-Organic Framework |
title_sort | pb ii adsorption by a calcium metal organic framework |
topic | metal-organic framework green synthesis heavy metal adsorption |
url | https://www.mdpi.com/2673-4583/12/1/74 |
work_keys_str_mv | AT minaaghaee pbiiadsorptionbyacalciummetalorganicframework AT faranakmanteghi pbiiadsorptionbyacalciummetalorganicframework |