A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity
Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahedral M4L4 cages across the lanthanide series.
| Príomhchruthaitheoirí: | , , , , , , , , , |
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| Formáid: | Alt |
| Teanga: | English |
| Foilsithe / Cruthaithe: |
Nature Portfolio
2018-02-01
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| Sraith: | Nature Communications |
| Rochtain ar líne: | https://doi.org/10.1038/s41467-018-02940-7 |