Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria

This study evaluates the potential deleterious impact of untreated waste water discharged into an unlined pit by the Nigerian National Petroleum Company (NNPC) on the groundwater quality of Umuakpara community in Osisioma, Abia state. Its overarching objective is to assess potential contaminant sour...

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Main Authors: Joseph Ikechukwu. Nwachukwu, Chinelo Lois. Gilbert, Michael A. Nwachukwu, Paul C. Njoku, P. Uzoije, T.E. Ebe, Chika V. Nwachukwu, S.E. Egbom
Format: Article
Language:English
Published: Elsevier 2024-04-01
Series:Waste Management Bulletin
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2949750724000105
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author Joseph Ikechukwu. Nwachukwu
Chinelo Lois. Gilbert
Michael A. Nwachukwu
Paul C. Njoku
P. Uzoije
T.E. Ebe
Chika V. Nwachukwu
S.E. Egbom
author_facet Joseph Ikechukwu. Nwachukwu
Chinelo Lois. Gilbert
Michael A. Nwachukwu
Paul C. Njoku
P. Uzoije
T.E. Ebe
Chika V. Nwachukwu
S.E. Egbom
author_sort Joseph Ikechukwu. Nwachukwu
collection DOAJ
description This study evaluates the potential deleterious impact of untreated waste water discharged into an unlined pit by the Nigerian National Petroleum Company (NNPC) on the groundwater quality of Umuakpara community in Osisioma, Abia state. Its overarching objective is to assess potential contaminant sources, distribution in groundwater using diverse techniques. Water samples collected from 14 domestic wells in two contrasting seasons (Rainy and Dry) were analyzed for Polynuclear Aromatic Hydrocarbons (PAHs) using Gas chromatography (GC). Vertical Electric Sounding (VES) technique was employed to determine the depth to water table and soil lithological layers required for good understanding of contaminants behavior along groundwater flow path. Pearson product moment correlation coefficient (r) and One-way ANOVA were used to define the interactions of detected PAHs and spatial variation in means of the PAHs components (p < 0.05) respectively. Five (5) priority PAHs were found in groundwater samples which generally measured above the WHO (2011) maximum permissible limit for PAHs in drinking water (0.001 mg/l). However, the levels of individual PAHs in each borehole were found to be lower than the USEPA permissible limit for each PAH. Phenanthrene recorded the highest mean concentration of 0.011214 (0.00106 ± 0.01650) mg/l, while Fluoranthene had the lowest mean concentration between N.D (Not detected) − 0.00216 (0.0004060 ± 0.00027136) mg/l. Significant spatial variability of PAH existed across sampled boreholes whereas strong correlations were noted among the respective PAH components at P < 0.01. Findings ultimately informed the design of a novel Composite Filter for Treatment of Hydrocarbon Contaminated Waters.
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spelling doaj.art-9d937dd592914c4995c6f3ea83682af22024-03-28T06:40:28ZengElsevierWaste Management Bulletin2949-75072024-04-0121229238Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, NigeriaJoseph Ikechukwu. Nwachukwu0Chinelo Lois. Gilbert1Michael A. Nwachukwu2Paul C. Njoku3P. Uzoije4T.E. Ebe5Chika V. Nwachukwu6S.E. Egbom7Department of Environmental Management, Federal University of Technology, Owerri, Nigeria; Corresponding author.Department of Environmental Management, Federal University of Technology, Owerri, NigeriaDepartment of Environmental Management, Federal University of Technology, Owerri, NigeriaDepartment of Environmental Management, Federal University of Technology, Owerri, NigeriaDepartment of Environmental Management, Federal University of Technology, Owerri, NigeriaDepartment of Environmental Management, Federal University of Technology, Owerri, NigeriaDepartment of Petroleum Engineering, Federal University of Technology, Owerri, NigeriaDepartment of Environmental Health, Federal University of Technology, Owerri, NigeriaThis study evaluates the potential deleterious impact of untreated waste water discharged into an unlined pit by the Nigerian National Petroleum Company (NNPC) on the groundwater quality of Umuakpara community in Osisioma, Abia state. Its overarching objective is to assess potential contaminant sources, distribution in groundwater using diverse techniques. Water samples collected from 14 domestic wells in two contrasting seasons (Rainy and Dry) were analyzed for Polynuclear Aromatic Hydrocarbons (PAHs) using Gas chromatography (GC). Vertical Electric Sounding (VES) technique was employed to determine the depth to water table and soil lithological layers required for good understanding of contaminants behavior along groundwater flow path. Pearson product moment correlation coefficient (r) and One-way ANOVA were used to define the interactions of detected PAHs and spatial variation in means of the PAHs components (p < 0.05) respectively. Five (5) priority PAHs were found in groundwater samples which generally measured above the WHO (2011) maximum permissible limit for PAHs in drinking water (0.001 mg/l). However, the levels of individual PAHs in each borehole were found to be lower than the USEPA permissible limit for each PAH. Phenanthrene recorded the highest mean concentration of 0.011214 (0.00106 ± 0.01650) mg/l, while Fluoranthene had the lowest mean concentration between N.D (Not detected) − 0.00216 (0.0004060 ± 0.00027136) mg/l. Significant spatial variability of PAH existed across sampled boreholes whereas strong correlations were noted among the respective PAH components at P < 0.01. Findings ultimately informed the design of a novel Composite Filter for Treatment of Hydrocarbon Contaminated Waters.http://www.sciencedirect.com/science/article/pii/S2949750724000105WasteGroundwaterContaminationAdvectionPolynuclear aromatic hydro carbons
spellingShingle Joseph Ikechukwu. Nwachukwu
Chinelo Lois. Gilbert
Michael A. Nwachukwu
Paul C. Njoku
P. Uzoije
T.E. Ebe
Chika V. Nwachukwu
S.E. Egbom
Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
Waste Management Bulletin
Waste
Groundwater
Contamination
Advection
Polynuclear aromatic hydro carbons
title Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
title_full Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
title_fullStr Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
title_full_unstemmed Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
title_short Assessment of groundwater contamination by effluent discharged PAH at NNPC depot in Osisioma, Abia State, Nigeria
title_sort assessment of groundwater contamination by effluent discharged pah at nnpc depot in osisioma abia state nigeria
topic Waste
Groundwater
Contamination
Advection
Polynuclear aromatic hydro carbons
url http://www.sciencedirect.com/science/article/pii/S2949750724000105
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