NASICON-type Na3V2(PO4)3
Single crystals of the title compound, trisodium divanadium(III) tris(orthophosphate), were grown from a self-flux in the system Na4P2O7–NaVP2O7. Na3V2(PO4)3 belongs to the family of NASICON-related structures and is built up from isolated [VO6] octahedra (3. symmetry) and [PO4] tetrah...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810002801 |
| _version_ | 1818948308420263936 |
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| author | Igor V. Zatovsky |
| author_facet | Igor V. Zatovsky |
| author_sort | Igor V. Zatovsky |
| collection | DOAJ |
| description | Single crystals of the title compound, trisodium divanadium(III) tris(orthophosphate), were grown from a self-flux in the system Na4P2O7–NaVP2O7. Na3V2(PO4)3 belongs to the family of NASICON-related structures and is built up from isolated [VO6] octahedra (3. symmetry) and [PO4] tetrahedra (.2 symmetry) interlinked via corners to establish the framework anion [V2(PO4)3]3−. The two independent Na+ cations are partially occupied [site-occupancy factors = 0.805 (18) and 0.731 (7)] and are located in channels with two different oxygen environments, viz sixfold coordination for the first (overline{3}. symmetry) and eightfold for the second (.2 symmetry) Na+ cation. |
| first_indexed | 2024-12-20T08:44:44Z |
| format | Article |
| id | doaj.art-9d9e6672a26841f58343a7fddb9ba971 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:44:44Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9d9e6672a26841f58343a7fddb9ba9712022-12-21T19:46:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662i12i1210.1107/S1600536810002801NASICON-type Na3V2(PO4)3Igor V. ZatovskySingle crystals of the title compound, trisodium divanadium(III) tris(orthophosphate), were grown from a self-flux in the system Na4P2O7–NaVP2O7. Na3V2(PO4)3 belongs to the family of NASICON-related structures and is built up from isolated [VO6] octahedra (3. symmetry) and [PO4] tetrahedra (.2 symmetry) interlinked via corners to establish the framework anion [V2(PO4)3]3−. The two independent Na+ cations are partially occupied [site-occupancy factors = 0.805 (18) and 0.731 (7)] and are located in channels with two different oxygen environments, viz sixfold coordination for the first (overline{3}. symmetry) and eightfold for the second (.2 symmetry) Na+ cation.http://scripts.iucr.org/cgi-bin/paper?S1600536810002801 |
| spellingShingle | Igor V. Zatovsky NASICON-type Na3V2(PO4)3 Acta Crystallographica Section E |
| title | NASICON-type Na3V2(PO4)3 |
| title_full | NASICON-type Na3V2(PO4)3 |
| title_fullStr | NASICON-type Na3V2(PO4)3 |
| title_full_unstemmed | NASICON-type Na3V2(PO4)3 |
| title_short | NASICON-type Na3V2(PO4)3 |
| title_sort | nasicon type na3v2 po4 3 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810002801 |
| work_keys_str_mv | AT igorvzatovsky nasicontypena3v2po43 |