Effect of Water Saturation on H<sub>2</sub> and CO Solubility in Hydrocarbons

The effect of water on the solubility of syngas in hydrocarbons has typically been ignored when developing models for Fischer-Tropsch slurry bubble column reactors (SBCR), despite water being a major by-product. Therefore, a generalized correlation was developed to predict water solubility in hydroc...

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Bibliographic Details
Main Author: Omar M. Basha
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:ChemEngineering
Subjects:
Online Access:https://www.mdpi.com/2305-7084/3/1/21
Description
Summary:The effect of water on the solubility of syngas in hydrocarbons has typically been ignored when developing models for Fischer-Tropsch slurry bubble column reactors (SBCR), despite water being a major by-product. Therefore, a generalized correlation was developed to predict water solubility in hydrocarbons at high temperatures, and was used to calculate the effect of water saturation on H<sub>2</sub> and CO solubility in hydrocarbons using the Span Wagner equation of state. The presence of water was shown to have a much more significant effect on H<sub>2</sub> solubility in hydrocarbons, compared to CO.
ISSN:2305-7084