Spring and surface water quality of the Cyprus ophiolites
A survey of surface, spring and borehole waters associated with the ophiolite rocks of Cyprus shows five broad water types (1) Mg-HCO<sub>3</sub>, (2) Na-SO<sub>4</sub>-Cl-HCO<sub>3</sub>, (3) Na-Ca-Cl-SO<sub>4</sub>-OH-CO<sub>3</sub>, (4)...
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| Format: | Article |
| Language: | English |
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Copernicus Publications
2002-01-01
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| Series: | Hydrology and Earth System Sciences |
| Online Access: | http://www.hydrol-earth-syst-sci.net/6/797/2002/hess-6-797-2002.pdf |
| _version_ | 1811334458300694528 |
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| author | C. Neal C. Neal P. Shand |
| author_facet | C. Neal C. Neal P. Shand |
| author_sort | C. Neal |
| collection | DOAJ |
| description | A survey of surface, spring and borehole waters associated with the ophiolite rocks of Cyprus shows five broad water types (1) Mg-HCO<sub>3</sub>, (2) Na-SO<sub>4</sub>-Cl-HCO<sub>3</sub>, (3) Na-Ca-Cl-SO<sub>4</sub>-OH-CO<sub>3</sub>, (4) Na-Cl-SO<sub>4</sub> and (5) Ca-SO<sub>4</sub>. The waters represent a progression in chemical reactivity from surface waters that evolve within a groundwater setting due to hydrolysis of the basic/ultrabasic rock as modified by CO<sub>2</sub>-weathering. An increase in salinity is also observed which is due to mixing with a saline end-member (modified sea-water) and dissolution of gypsum/anhydrite. In some cases, the waters have pH values greater than 11. Such high values are associated with low temperature serpentinisation reactions. The system is a net sink for CO<sub>2</sub>. This feature is related not only to the hydrolysis of the primary minerals in the rock, but also to CaCO<sub>3</sub> or Ca-Mg-CO<sub>3</sub> solubility controls. Under hyperalkaline conditions, virtually all the carbon dioxide is lost from the water due to the sufficiently high calcium levels and carbonate buffering is then insignificant. Calcium sulphate solubility controls may also be operative when calcium and sulphate concentrations are particularly high.</p> <p style='line-height: 20px;'><b>Keywords: </b>Cyprus, Troodos, ophiolite, serpentinisation, spring, stream, water quality, bromide, iodine, boron, trace elements, hyperalkaline.</p> |
| first_indexed | 2024-04-13T17:08:10Z |
| format | Article |
| id | doaj.art-9e029b96013d46c3b9770bc97747eb8b |
| institution | Directory Open Access Journal |
| issn | 1027-5606 1607-7938 |
| language | English |
| last_indexed | 2024-04-13T17:08:10Z |
| publishDate | 2002-01-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Hydrology and Earth System Sciences |
| spelling | doaj.art-9e029b96013d46c3b9770bc97747eb8b2022-12-22T02:38:22ZengCopernicus PublicationsHydrology and Earth System Sciences1027-56061607-79382002-01-0165797817Spring and surface water quality of the Cyprus ophiolitesC. NealC. NealP. ShandA survey of surface, spring and borehole waters associated with the ophiolite rocks of Cyprus shows five broad water types (1) Mg-HCO<sub>3</sub>, (2) Na-SO<sub>4</sub>-Cl-HCO<sub>3</sub>, (3) Na-Ca-Cl-SO<sub>4</sub>-OH-CO<sub>3</sub>, (4) Na-Cl-SO<sub>4</sub> and (5) Ca-SO<sub>4</sub>. The waters represent a progression in chemical reactivity from surface waters that evolve within a groundwater setting due to hydrolysis of the basic/ultrabasic rock as modified by CO<sub>2</sub>-weathering. An increase in salinity is also observed which is due to mixing with a saline end-member (modified sea-water) and dissolution of gypsum/anhydrite. In some cases, the waters have pH values greater than 11. Such high values are associated with low temperature serpentinisation reactions. The system is a net sink for CO<sub>2</sub>. This feature is related not only to the hydrolysis of the primary minerals in the rock, but also to CaCO<sub>3</sub> or Ca-Mg-CO<sub>3</sub> solubility controls. Under hyperalkaline conditions, virtually all the carbon dioxide is lost from the water due to the sufficiently high calcium levels and carbonate buffering is then insignificant. Calcium sulphate solubility controls may also be operative when calcium and sulphate concentrations are particularly high.</p> <p style='line-height: 20px;'><b>Keywords: </b>Cyprus, Troodos, ophiolite, serpentinisation, spring, stream, water quality, bromide, iodine, boron, trace elements, hyperalkaline.</p>http://www.hydrol-earth-syst-sci.net/6/797/2002/hess-6-797-2002.pdf |
| spellingShingle | C. Neal C. Neal P. Shand Spring and surface water quality of the Cyprus ophiolites Hydrology and Earth System Sciences |
| title | Spring and surface water quality of the Cyprus ophiolites |
| title_full | Spring and surface water quality of the Cyprus ophiolites |
| title_fullStr | Spring and surface water quality of the Cyprus ophiolites |
| title_full_unstemmed | Spring and surface water quality of the Cyprus ophiolites |
| title_short | Spring and surface water quality of the Cyprus ophiolites |
| title_sort | spring and surface water quality of the cyprus ophiolites |
| url | http://www.hydrol-earth-syst-sci.net/6/797/2002/hess-6-797-2002.pdf |
| work_keys_str_mv | AT cneal springandsurfacewaterqualityofthecyprusophiolites AT cneal springandsurfacewaterqualityofthecyprusophiolites AT pshand springandsurfacewaterqualityofthecyprusophiolites |