The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy
Aftermarket additives are used to enhance the performance of internal combustion engines in specific aspects such as reducing wear, increasing power, and improving fuel economy. Despite their advantages, they can sometimes cause corrosion-related problems. This research evaluated the corrosiveness o...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-03-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/17/6/1326 |
| _version_ | 1797240189900292096 |
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| author | Oriana Palma Calabokis Yamid Nuñez de la Rosa Paulo César Borges Tiago Cousseau |
| author_facet | Oriana Palma Calabokis Yamid Nuñez de la Rosa Paulo César Borges Tiago Cousseau |
| author_sort | Oriana Palma Calabokis |
| collection | DOAJ |
| description | Aftermarket additives are used to enhance the performance of internal combustion engines in specific aspects such as reducing wear, increasing power, and improving fuel economy. Despite their advantages, they can sometimes cause corrosion-related problems. This research evaluated the corrosiveness of four aftermarket additives on the corrosion of a high-leaded tin bronze alloy over 28 days at 80 °C in immersion tests. Among the evaluated products, three showed corrosive effects ranging from intermediate to severe. Notably, the visual appearance of the surfaces often did not indicate the underlying corrosive damage. Therefore, the assessment of corrosiveness was based on chemical characterizations conducted on both the drained oils and the bronze surfaces. The study found minimal oil degradation under the testing conditions, indicating that the primary cause of corrosion was the interaction between the specific additives and the metal elements of the alloy, rather than oil degradation itself. A direct correlation was observed between the dissolution of lead and copper and the adsorption of S and Cl-containing additives on the surfaces, respectively. The corrosive impact of Cl-containing additives in aftermarket formulations was significantly reduced when mixed with engine oil SAE 10W-30 (at a 25:1 ratio), suggesting a mitigated effect in combined formulations, which is the recommended usage for engines. |
| first_indexed | 2024-04-24T18:03:29Z |
| format | Article |
| id | doaj.art-9e068d50e12d49919a3eee0f3099ffd6 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-04-24T18:03:29Z |
| publishDate | 2024-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-9e068d50e12d49919a3eee0f3099ffd62024-03-27T13:52:33ZengMDPI AGMaterials1996-19442024-03-01176132610.3390/ma17061326The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze AlloyOriana Palma Calabokis0Yamid Nuñez de la Rosa1Paulo César Borges2Tiago Cousseau3GrMatS Group, Universidade Tecnológica Federal do Paraná, Curitiba 81280-340, BrazilGrMatS Group, Universidade Tecnológica Federal do Paraná, Curitiba 81280-340, BrazilGrMatS Group, Universidade Tecnológica Federal do Paraná, Curitiba 81280-340, BrazilGrMatS Group, Universidade Tecnológica Federal do Paraná, Curitiba 81280-340, BrazilAftermarket additives are used to enhance the performance of internal combustion engines in specific aspects such as reducing wear, increasing power, and improving fuel economy. Despite their advantages, they can sometimes cause corrosion-related problems. This research evaluated the corrosiveness of four aftermarket additives on the corrosion of a high-leaded tin bronze alloy over 28 days at 80 °C in immersion tests. Among the evaluated products, three showed corrosive effects ranging from intermediate to severe. Notably, the visual appearance of the surfaces often did not indicate the underlying corrosive damage. Therefore, the assessment of corrosiveness was based on chemical characterizations conducted on both the drained oils and the bronze surfaces. The study found minimal oil degradation under the testing conditions, indicating that the primary cause of corrosion was the interaction between the specific additives and the metal elements of the alloy, rather than oil degradation itself. A direct correlation was observed between the dissolution of lead and copper and the adsorption of S and Cl-containing additives on the surfaces, respectively. The corrosive impact of Cl-containing additives in aftermarket formulations was significantly reduced when mixed with engine oil SAE 10W-30 (at a 25:1 ratio), suggesting a mitigated effect in combined formulations, which is the recommended usage for engines.https://www.mdpi.com/1996-1944/17/6/1326copper alloyscorrosionaftermarket additivesCl-containing additivesS-containing additives |
| spellingShingle | Oriana Palma Calabokis Yamid Nuñez de la Rosa Paulo César Borges Tiago Cousseau The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy Materials copper alloys corrosion aftermarket additives Cl-containing additives S-containing additives |
| title | The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy |
| title_full | The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy |
| title_fullStr | The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy |
| title_full_unstemmed | The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy |
| title_short | The Corrosive Effects of Aftermarket Oil Additives on High-Leaded Tin Bronze Alloy |
| title_sort | corrosive effects of aftermarket oil additives on high leaded tin bronze alloy |
| topic | copper alloys corrosion aftermarket additives Cl-containing additives S-containing additives |
| url | https://www.mdpi.com/1996-1944/17/6/1326 |
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