Photocatalytic Removal of Ciprofloxacin in Water by Novel Sandwich-like CuFe<sub>2</sub>O<sub>4</sub> on rGO/Halloysite Material: Insights into Kinetics and Intermediate Reactive Radicals

In this study, the CuFe<sub>2</sub>O<sub>4</sub> on rGO/halloysite material was made in an uncomplicated manner. The catalyst has a sandwich-like shape with a uniform coating of the active phase on the rGO sheets and halloysite tubes. The catalyst’s large specific surface are...

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Bibliographic Details
Main Authors: Ha-Son Ngo, Thi-Linh Nguyen, Ngoc-Tuan Tran, Hanh-Chi Le
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/15/8/1569
Description
Summary:In this study, the CuFe<sub>2</sub>O<sub>4</sub> on rGO/halloysite material was made in an uncomplicated manner. The catalyst has a sandwich-like shape with a uniform coating of the active phase on the rGO sheets and halloysite tubes. The catalyst’s large specific surface area (130 m<sup>2</sup>/g) and small band gap energy (1.9 eV) allow it to adsorb photons and photocatalyze organic contaminants effectively. In approximately 1 h of light, the catalyst showed high performance in achieving almost complete conversion in photodegrading CIP for an initial CIP concentration of 20 ppm. A pseudo-first-order rate law was followed by the process, as revealed by the experimental results. In addition, the pH effect and the contribution of intermediate reactive radicals that emerged during the photochemical process were explored. The results indicated that hydroxyl radicals and holes had a major impact on CIP decomposition, suggesting that the addition of these radicals could enhance CIP degradation efficiency at a larger scale. This study also confirmed the superiority of catalysis and photochemical processes in environmental treatments by the neutral pH values.
ISSN:2073-4441