In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT

Two aircraft instruments for the measurement of total odd nitrogen (NO<sub>y</sub>) were compared side by side aboard a Learjet A35 in April 2003 during a campaign of the AFO2000 project SPURT (Spurengastransport in der Tropopausenregion). The instruments albeit employing the same measur...

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Main Authors: H. Fischer, U. Schmidt, D. Brunner, M. I. Hegglin, A. Volz-Thomas, H.-W. Pätz
Format: Article
Language:English
Published: Copernicus Publications 2006-01-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/6/2401/2006/acp-6-2401-2006.pdf
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author H. Fischer
U. Schmidt
D. Brunner
M. I. Hegglin
A. Volz-Thomas
H.-W. Pätz
author_facet H. Fischer
U. Schmidt
D. Brunner
M. I. Hegglin
A. Volz-Thomas
H.-W. Pätz
author_sort H. Fischer
collection DOAJ
description Two aircraft instruments for the measurement of total odd nitrogen (NO<sub>y</sub>) were compared side by side aboard a Learjet A35 in April 2003 during a campaign of the AFO2000 project SPURT (Spurengastransport in der Tropopausenregion). The instruments albeit employing the same measurement principle (gold converter and chemiluminescence) had different inlet configurations. The ECO-Physics instrument operated by ETH-Zürich in SPURT had the gold converter mounted outside the aircraft, whereas the instrument operated by FZ-Jülich in the European project MOZAIC III (Measurements of ozone, water vapour, carbon monoxide and nitrogen oxides aboard Airbus A340 in-service aircraft) employed a Rosemount probe with 80 cm of FEP-tubing connecting the inlet to the gold converter. The NO<sub>y</sub> concentrations during the flight ranged between 0.3 and 3 ppb. The two data sets were compared in a blind fashion and each team followed its normal operating procedures. On average, the measurements agreed within 7%, i.e. within the combined uncertainty of the two instruments. This puts an upper limit on potential losses of HNO<sub>3</sub> in the Rosemount inlet of the MOZAIC instrument. Larger transient deviations were observed during periods after calibrations and when the aircraft entered the stratosphere. The time lag of the MOZAIC instrument observed in these instances is in accordance with the time constant of the MOZAIC inlet line determined in the laboratory for HNO<sub>3</sub>.
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spelling doaj.art-9e2adfa68bb649169f0697ecaffc9cc82022-12-22T00:42:55ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242006-01-016924012410In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURTH. FischerU. SchmidtD. BrunnerM. I. HegglinA. Volz-ThomasH.-W. PätzTwo aircraft instruments for the measurement of total odd nitrogen (NO<sub>y</sub>) were compared side by side aboard a Learjet A35 in April 2003 during a campaign of the AFO2000 project SPURT (Spurengastransport in der Tropopausenregion). The instruments albeit employing the same measurement principle (gold converter and chemiluminescence) had different inlet configurations. The ECO-Physics instrument operated by ETH-Zürich in SPURT had the gold converter mounted outside the aircraft, whereas the instrument operated by FZ-Jülich in the European project MOZAIC III (Measurements of ozone, water vapour, carbon monoxide and nitrogen oxides aboard Airbus A340 in-service aircraft) employed a Rosemount probe with 80 cm of FEP-tubing connecting the inlet to the gold converter. The NO<sub>y</sub> concentrations during the flight ranged between 0.3 and 3 ppb. The two data sets were compared in a blind fashion and each team followed its normal operating procedures. On average, the measurements agreed within 7%, i.e. within the combined uncertainty of the two instruments. This puts an upper limit on potential losses of HNO<sub>3</sub> in the Rosemount inlet of the MOZAIC instrument. Larger transient deviations were observed during periods after calibrations and when the aircraft entered the stratosphere. The time lag of the MOZAIC instrument observed in these instances is in accordance with the time constant of the MOZAIC inlet line determined in the laboratory for HNO<sub>3</sub>.http://www.atmos-chem-phys.net/6/2401/2006/acp-6-2401-2006.pdf
spellingShingle H. Fischer
U. Schmidt
D. Brunner
M. I. Hegglin
A. Volz-Thomas
H.-W. Pätz
In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
Atmospheric Chemistry and Physics
title In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
title_full In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
title_fullStr In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
title_full_unstemmed In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
title_short In-situ comparison of the NO<sub>y</sub> instruments flown in MOZAIC and SPURT
title_sort in situ comparison of the no sub y sub instruments flown in mozaic and spurt
url http://www.atmos-chem-phys.net/6/2401/2006/acp-6-2401-2006.pdf
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