Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
This is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of...
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Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences
2024-02-01
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Series: | Kuangchan zonghe liyong |
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Online Access: | http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020 |
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author | Bo YU Tingshu HE Xin WANG Hanbing HE Yubin WANG |
author_facet | Bo YU Tingshu HE Xin WANG Hanbing HE Yubin WANG |
author_sort | Bo YU |
collection | DOAJ |
description | This is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of Pb2+ and Zn2+ on the floatability of chalcopyrite was studied by single mineral flotation test, solution chemical calculation, Zeta potential and XPS detection. The results show that Pb2+ and Zn2+ are adsorbed on the surface of chalcopyrite, which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite, and the inhibition increases with the increase of pH value. According to the flotation test results, zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH, which has an inhibitory effect on the flotation of chalcopyrite. Therefore, the inhibitory effect of Zn2+ on the flotation of chalcopyrite is more significant than that of Pb2+ and XPS results show that Pb2+ and Zn2+ can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption, thus inhibiting the floatability of chalcopyrite. |
first_indexed | 2024-04-24T20:23:57Z |
format | Article |
id | doaj.art-9e41cb456a05477694753d984813732a |
institution | Directory Open Access Journal |
issn | 1000-6532 |
language | zho |
last_indexed | 2024-04-24T20:23:57Z |
publishDate | 2024-02-01 |
publisher | Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences |
record_format | Article |
series | Kuangchan zonghe liyong |
spelling | doaj.art-9e41cb456a05477694753d984813732a2024-03-22T07:31:13ZzhoInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesKuangchan zonghe liyong1000-65322024-02-0145115515910.3969/j.issn.1000-6532.2024.01.0202024-01yuboEffect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its MechanismBo YU0Tingshu HE1Xin WANG2Hanbing HE3Yubin WANG4School of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaThis is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of Pb2+ and Zn2+ on the floatability of chalcopyrite was studied by single mineral flotation test, solution chemical calculation, Zeta potential and XPS detection. The results show that Pb2+ and Zn2+ are adsorbed on the surface of chalcopyrite, which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite, and the inhibition increases with the increase of pH value. According to the flotation test results, zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH, which has an inhibitory effect on the flotation of chalcopyrite. Therefore, the inhibitory effect of Zn2+ on the flotation of chalcopyrite is more significant than that of Pb2+ and XPS results show that Pb2+ and Zn2+ can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption, thus inhibiting the floatability of chalcopyrite.http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020mineral processing engineeringchalcopyritelead zinc ionfloatabilityinhibition |
spellingShingle | Bo YU Tingshu HE Xin WANG Hanbing HE Yubin WANG Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism Kuangchan zonghe liyong mineral processing engineering chalcopyrite lead zinc ion floatability inhibition |
title | Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism |
title_full | Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism |
title_fullStr | Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism |
title_full_unstemmed | Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism |
title_short | Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism |
title_sort | effect of pb2 zn2 on floatability of chalcopyrite in z 200 system and its mechanism |
topic | mineral processing engineering chalcopyrite lead zinc ion floatability inhibition |
url | http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020 |
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