Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism

This is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of...

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Main Authors: Bo YU, Tingshu HE, Xin WANG, Hanbing HE, Yubin WANG
Format: Article
Language:zho
Published: Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences 2024-02-01
Series:Kuangchan zonghe liyong
Subjects:
Online Access:http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020
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author Bo YU
Tingshu HE
Xin WANG
Hanbing HE
Yubin WANG
author_facet Bo YU
Tingshu HE
Xin WANG
Hanbing HE
Yubin WANG
author_sort Bo YU
collection DOAJ
description This is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of Pb2+ and Zn2+ on the floatability of chalcopyrite was studied by single mineral flotation test, solution chemical calculation, Zeta potential and XPS detection. The results show that Pb2+ and Zn2+ are adsorbed on the surface of chalcopyrite, which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite, and the inhibition increases with the increase of pH value. According to the flotation test results, zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH, which has an inhibitory effect on the flotation of chalcopyrite. Therefore, the inhibitory effect of Zn2+ on the flotation of chalcopyrite is more significant than that of Pb2+ and XPS results show that Pb2+ and Zn2+ can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption, thus inhibiting the floatability of chalcopyrite.
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spelling doaj.art-9e41cb456a05477694753d984813732a2024-03-22T07:31:13ZzhoInstitute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesKuangchan zonghe liyong1000-65322024-02-0145115515910.3969/j.issn.1000-6532.2024.01.0202024-01yuboEffect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its MechanismBo YU0Tingshu HE1Xin WANG2Hanbing HE3Yubin WANG4School of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaSchool of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, ChinaThis is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of Pb2+ and Zn2+ on the floatability of chalcopyrite was studied by single mineral flotation test, solution chemical calculation, Zeta potential and XPS detection. The results show that Pb2+ and Zn2+ are adsorbed on the surface of chalcopyrite, which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite, and the inhibition increases with the increase of pH value. According to the flotation test results, zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH, which has an inhibitory effect on the flotation of chalcopyrite. Therefore, the inhibitory effect of Zn2+ on the flotation of chalcopyrite is more significant than that of Pb2+ and XPS results show that Pb2+ and Zn2+ can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption, thus inhibiting the floatability of chalcopyrite.http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020mineral processing engineeringchalcopyritelead zinc ionfloatabilityinhibition
spellingShingle Bo YU
Tingshu HE
Xin WANG
Hanbing HE
Yubin WANG
Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
Kuangchan zonghe liyong
mineral processing engineering
chalcopyrite
lead zinc ion
floatability
inhibition
title Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
title_full Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
title_fullStr Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
title_full_unstemmed Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
title_short Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
title_sort effect of pb2 zn2 on floatability of chalcopyrite in z 200 system and its mechanism
topic mineral processing engineering
chalcopyrite
lead zinc ion
floatability
inhibition
url http://www.kczhly.com/en/article/doi/10.3969/j.issn.1000-6532.2024.01.020
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AT xinwang effectofpb2zn2onfloatabilityofchalcopyriteinz200systemanditsmechanism
AT hanbinghe effectofpb2zn2onfloatabilityofchalcopyriteinz200systemanditsmechanism
AT yubinwang effectofpb2zn2onfloatabilityofchalcopyriteinz200systemanditsmechanism