Tailoring the corrosion and tribological performance of Ti-modified MoS2-based films in simulated seawater

Film protection has become a crucial means to improve the corrosion and wear performance of key components in aggressive environment. In this study, the feasibility of using MoS2-based modified films in artificial seawater (3.5% NaCl solution) was evaluated by co-deposition of Ti to produce Ti–MoS2...

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Bibliographic Details
Main Authors: Xiangru Shi, Peihua He, Shangqi Sun, Jian Chen, Ben D. Beake, Tomasz W. Liskiewicz, Xin Zhang, Zehua Zhou
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422014685
Description
Summary:Film protection has become a crucial means to improve the corrosion and wear performance of key components in aggressive environment. In this study, the feasibility of using MoS2-based modified films in artificial seawater (3.5% NaCl solution) was evaluated by co-deposition of Ti to produce Ti–MoS2 composite and Ti/MoS2 multilayer films. The microstructure, wettability, mechanical, tribological and corrosion behavior of the Ti-modified MoS2-based films was contrasted to pure MoS2 film. The results show that the incorporation of Ti not only improves densification, but also promotes a transformation from a columnar to an amorphous film structure, leading to the improvement of mechanical properties of Ti–MoS2 composite film and Ti/MoS2 multilayer film. The friction coefficient curves of all of the three MoS2-based film in 3.5 wt% NaCl solution show stable values during the sliding process. The advantage of the preferential (002) growth orientation, improved mechanical properties and reduced hydrophobicity for both of the Ti-modified MoS2 films caused the decreased friction coefficient and wear rate in NaCl solution. The electrochemical results before and after friction show that the ranking of corrosion resistance is Ti/MoS2 multilayer > Ti–MoS2 composite film > pure MoS2 film, which is attributed to the compact microstructure and the presence of surface passive films.
ISSN:2238-7854