Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model

Amorphous Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses were prepared by melt quench technique. Surface morphology with the chemical composition of the prepared glass was examined using SEM and EDS analysis respectively. Dielectric properties and a.c. conductivity of the multicomponent Ge10−xSe...

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Main Authors: Pravin Kumar Singh, S.K. Sharma, S.K. Tripathi, D.K. Dwivedi
Format: Article
Language:English
Published: Elsevier 2019-03-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379718324525
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author Pravin Kumar Singh
S.K. Sharma
S.K. Tripathi
D.K. Dwivedi
author_facet Pravin Kumar Singh
S.K. Sharma
S.K. Tripathi
D.K. Dwivedi
author_sort Pravin Kumar Singh
collection DOAJ
description Amorphous Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses were prepared by melt quench technique. Surface morphology with the chemical composition of the prepared glass was examined using SEM and EDS analysis respectively. Dielectric properties and a.c. conductivity of the multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses have been examined in the frequency range 100 Hz–1 MHz and temperature range 303–328 K. It was noticed that dielectric constant and dielectric loss decreases with the increase of frequency and increases with the increase of temperatures. Frequency and temperature dependence of dielectric constant was explained by orientational polarization. The variation of dielectric loss with frequency and temperature was explained by conduction loss and theory of single polaron hopping of charge carriers suggested by Elliot and Shimakawa for chalcogenide glasses. The experimental results show that a.c. conductivity follows the power law ωs where s < 1 and value of s decreases with the increase of temperature. The present findings of a.c. conductivity and variation of s with temperatures are reasonably well interpreted in terms of CBH model. Keywords: Chalcogenide glasses, Ac conductivity, Dielectric relaxation, CBH model, Activation energy
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spelling doaj.art-9e5e39bfa13f43d1bf1fdf543ce698422022-12-21T23:49:47ZengElsevierResults in Physics2211-37972019-03-0112223236Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH modelPravin Kumar Singh0S.K. Sharma1S.K. Tripathi2D.K. Dwivedi3Amorphous Semiconductor Research Lab, Department of Applied Science, M. M. M. University of Technology, Gorakhpur 273010, IndiaDepartment of Physics, Harcourt Butler Technical University, Kanpur 208002, IndiaDepartment of Physics, Punjab University, Chandigarh 160014, IndiaAmorphous Semiconductor Research Lab, Department of Applied Science, M. M. M. University of Technology, Gorakhpur 273010, IndiaAmorphous Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses were prepared by melt quench technique. Surface morphology with the chemical composition of the prepared glass was examined using SEM and EDS analysis respectively. Dielectric properties and a.c. conductivity of the multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses have been examined in the frequency range 100 Hz–1 MHz and temperature range 303–328 K. It was noticed that dielectric constant and dielectric loss decreases with the increase of frequency and increases with the increase of temperatures. Frequency and temperature dependence of dielectric constant was explained by orientational polarization. The variation of dielectric loss with frequency and temperature was explained by conduction loss and theory of single polaron hopping of charge carriers suggested by Elliot and Shimakawa for chalcogenide glasses. The experimental results show that a.c. conductivity follows the power law ωs where s < 1 and value of s decreases with the increase of temperature. The present findings of a.c. conductivity and variation of s with temperatures are reasonably well interpreted in terms of CBH model. Keywords: Chalcogenide glasses, Ac conductivity, Dielectric relaxation, CBH model, Activation energyhttp://www.sciencedirect.com/science/article/pii/S2211379718324525
spellingShingle Pravin Kumar Singh
S.K. Sharma
S.K. Tripathi
D.K. Dwivedi
Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
Results in Physics
title Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
title_full Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
title_fullStr Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
title_full_unstemmed Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
title_short Study of dielectric relaxation and thermally activated a.c. conduction in multicomponent Ge10−xSe60Te30Inx (0 ≤ x ≤ 6) chalcogenide glasses using CBH model
title_sort study of dielectric relaxation and thermally activated a c conduction in multicomponent ge10 xse60te30inx 0 ≤ x ≤ 6 chalcogenide glasses using cbh model
url http://www.sciencedirect.com/science/article/pii/S2211379718324525
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