Chloride Binding Properties of a Macrocyclic Receptor Equipped with an Acetylide Gold(I) Complex: Synthesis, Characterization, Reactivity, and Cytotoxicity Studies

Chloride Binding Properties of a Macrocyclic Receptor Equipped with an Acetylide Gold(I) Complex: Synthesis, Characterization, Reactivity, and Cytotoxicity Studies

In this work, we report the synthesis and characterization of a mono-nuclear “two wall” aryl-extended calix[4]pyrrole receptor (<b>2Au</b>) decorated with an acetylide-gold(I)-PTA complex at its upper rim. We describe the <sup>1</sup>H NMR titration experiments of <b>2A...

Full description

Bibliographic Details
Main Authors:	Andrea Rivoli, Gemma Aragay, María Concepción Gimeno, Pablo Ballester
Format:	Article
Language:	English
Published:	MDPI AG 2022-07-01
Series:	Inorganics
Subjects:	calix[4]pyrrole anion receptors acetylide gold(I) complexes cytotoxicity studies
Online Access:	https://www.mdpi.com/2304-6740/10/7/95

Similar Items

Ab Initio Rovibrational Spectroscopy of the Acetylide Anion
by: Benjamin Schröder
Published: (2023-07-01)

The first direct synthesis of β-unsubstituted meso-decamethylcalix[5]pyrrole
by: Luis Chacón-García, et al.
Published: (2009-01-01)

Resolving the Magnetic Asymmetry of the Inner Space in Self-assembled Dimeric Capsules Based on Tetraurea-calix[4]pyrrole Components
by: Mónica Espelt, et al.
Published: (2015-11-01)

Syntheses of Calix[4]Pyrroles by Amberlyst-15 Catalyzed Cyclocondensations of Pyrrole with Selected Ketones
by: Tanuja Bisht, et al.
Published: (2007-11-01)

Quantification of CH-π Interactions Using Calix[4]pyrrole Receptors as Model Systems
by: Gemma Aragay, et al.
Published: (2015-09-01)

Electrochemical Studies of the Cycloaddition Activity of Bismuth(III) Acetylides Towards Organic Azides Under Copper(I)-Catalyzed Conditions
by: Antonina L. Nazarova, et al.
Published: (2022-02-01)

Dinuclear Gold Complexes Supported by Wide Bite Angle Diphosphines for Preorganization-Induced Selective Dual-Gold Catalysis
by: Marianne Lankelma, et al.
Published: (2019-02-01)

Cytotoxic Gold(I) Complexes with Amidophosphine Ligands Containing Thiophene Moieties
by: Helen Goitia, et al.
Published: (2019-01-01)

Selective Transport of Ag(I) through a Polymer Inclusion Membrane Containing a Calix[4]pyrrole Derivative from Nitrate Aqueous Solutions
by: Anna Nowik-Zajac, et al.
Published: (2020-07-01)

Novel edifice calix[4]pyrrole derivatives as a potential sensor for the detection of analytes and in silico computational behaviour
by: Ajay L. Desai, et al.
Published: (2022-08-01)

Thermochemically Stable Liquid-Crystalline Gold(I) Complexes Showing Enhanced Room Temperature Phosphorescence
by: Yuki Kuroda, et al.
Published: (2019-04-01)

Use of Graphite Oxide and Graphene Oxide as Catalysts in the Synthesis of Dipyrromethane and Calix[4]pyrrole
by: Sweta Mishra, et al.
Published: (2011-08-01)

A Se···O bonding catalysis approach to the synthesis of calix[4]pyrroles
by: Qingzhe Tong, et al.
Published: (2022-03-01)

A ferrocene redox-active triazolium macrocycle that binds and senses chloride
by: Nicholas G. White, et al.
Published: (2012-02-01)

A New Series of Pyrrole-Based Chalcones: Synthesis and Evaluation of Antimicrobial Activity, Cytotoxicity, and Genotoxicity
by: Ahmet Özdemir, et al.
Published: (2017-11-01)

A Hydrido η1-Alkynyl Diplatinum Complex Obtained from a Phosphinito Phosphanido Complex and Trimethylsilylacetylene
by: Mario Latronico, et al.
Published: (2014-10-01)

Azocalixarene. 5: p-Substituted Azocalix4arenes as Extractants for Dichromate Anions
by: Hasalettin Deligöz, et al.
Published: (2008-06-01)

A theoretical study of the neutral and the double-charged cation of cyclo[8]pyrrole and its interaction with inorganic anions
by: Alkorta Ibon, et al.
Published: (2009-12-01)

Synthesis and cytotoxic activity of new indolylpyrrole derivatives
by: Mohamed A.A. Radwan, et al.
Published: (2021-07-01)

Carboxybetaine and Carboxybetaine Ester Derivatives of Tetra(dodecyloxyphenyl)-calix[4]resorcinarene: Synthesis, Self-Assembly and In Vitro Toxicity
by: Julia E. Morozova, et al.
Published: (2023-01-01)

Synthesis, characterisation and cytotoxicity of gold microwires for ultra-sensitive biosensor development
by: Nurul Akmal Che Lah, et al.
Published: (2021-02-01)

Fraisinib: a calixpyrrole derivative reducing A549 cell-derived NSCLC tumor in vivo acts as a ligand of the glycine-tRNA synthase, a new molecular target in oncology
by: Iméne Ben Toumia, et al.
Published: (2024-01-01)

Selective detection of fluoride based on a pyridinium n-phenolate-calix[4]pyrrole displacement assay: an undergraduate laboratory experiment
by: Karina Mannrich, et al.
Published: (2014-01-01)

Cytotoxic Furan- and Pyrrole-Containing Scalarane Sesterterpenoids Isolated from the Sponge <i>Scalarispongia</i> sp.
by: Yeon-Ju Lee, et al.
Published: (2019-02-01)

PEG-Modified <i>tert</i>-Octylcalix[8]arenes as Drug Delivery Nanocarriers of Silibinin
by: Desislava Budurova, et al.
Published: (2021-11-01)

Macrocycles and Supramolecules as Antioxidants: Excellent Scaffolds for Development of Potential Therapeutic Agents
by: Jung-Seop Lee, et al.
Published: (2020-09-01)

Terpyridine-Functionalized Calixarenes: Synthesis, Characterization and Anion Sensing Applications
by: Nicola Y. Edwards, et al.
Published: (2020-12-01)

Assessment of the cytotoxicity of chlorhexidine by employing an in vitro mammalian test system
by: Yi-Ching Li, et al.
Published: (2014-06-01)

Nitro-Substituted Dipyrrolyldiketone BF<sub>2</sub> Complexes as Electronic-State-Adjustable Anion-Responsive π-Electronic Systems
by: Atsuko Kuno, et al.
Published: (2021-01-01)

Chemical Constituents from the Stems of Tinospora sinensis and Their Bioactivity
by: Sio-Hong Lam, et al.
Published: (2018-10-01)

Isotopic labelling studies for a gold-catalysed skeletal rearrangement of alkynyl aziridines
by: Paul W. Davies, et al.
Published: (2011-06-01)

Synthesis and Cytotoxicity Assessment of Gold-coated Magnetic Iron Oxide Nanoparticles
by: M Keshtkar, et al.
Published: (2018-12-01)

Synthesis of “<i>All-Cis”</i> Trihydroxypiperidines from a Carbohydrate-Derived Ketone: Hints for the Design of New β-Gal and GCase Inhibitors
by: Maria Giulia Davighi, et al.
Published: (2020-10-01)

Biocompatibility and Cytotoxicity of Gold Nanoparticles: Recent Advances in Methodologies and Regulations
by: Małgorzata Kus-Liśkiewicz, et al.
Published: (2021-10-01)

Pegylated Gold Nanoparticles Conjugated with siRNA: Complexes Formation and Cytotoxicity
by: Elżbieta Okła, et al.
Published: (2023-04-01)

Cytotoxicity and Antimicrobial efficiency of gold (Au) nanoparticles formulated by green approach using Andrographis paniculata leaf extract
by: Viji Paramasivam, et al.
Published: (2023-07-01)

Cytotoxic Induction and Photoacoustic Imaging of Breast Cancer Cells Using Astaxanthin-Reduced Gold Nanoparticles
by: Subramaniyan Bharathiraja, et al.
Published: (2016-04-01)

Gold Nanoparticles as Monoanion Sensors through Modified Electrophilicity
by: Almudena Martí, et al.
Published: (2023-09-01)

Recent advances in macrocyclic arenes-based fluorescent indicator displacement assays
by: Qunpeng Duan, et al.
Published: (2022-07-01)

THE SOLID-STATE INCLUSION COMPLEX BETWEEN THE MONO-ANION OF CALIX[4]ARENE AND PROTONATED DIAMINO-BICYCLOUNDECANE
by: Oleksandr Shkurenko, et al.
Published: (2009-12-01)