trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate
The asymmetric unit of the title compound, [Ni(C6H6N2O)2(H2O)4](C7H5O3)2·4H2O, contains one-half of the complex cation with the NiII ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane ar...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002218 |
| _version_ | 1819291490991472640 |
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| author | Ibrahim Göker Zaman Nagihan Çaylak Delibaş Hacali Necefoğlu Tuncer Hökelek |
| author_facet | Ibrahim Göker Zaman Nagihan Çaylak Delibaş Hacali Necefoğlu Tuncer Hökelek |
| author_sort | Ibrahim Göker Zaman |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ni(C6H6N2O)2(H2O)4](C7H5O3)2·4H2O, contains one-half of the complex cation with the NiII ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the NiII ion [Ni—O = 2.052 (2) and 2.079 (2) Å] form a slightly distorted square-planar arrangement, which is completed up to a distorted octahedron by the two N atoms [Ni—N = 2.075 (3) Å] from two isonicotinamide ligands. In the anion, the carboxylate group is twisted from the attached benzene ring by 8.8 (3)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H...O and N—H...O hydrogen bonds, consolidates the crystal packing, which also exhibits π–π interactions between the benzene and pyridine rings, with centroid–centroid distances of 3.455 (2) and 3.621 (2) Å, respectively. |
| first_indexed | 2024-12-24T03:39:28Z |
| format | Article |
| id | doaj.art-9e8689d4d08e41459e58226119f0fba9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:39:28Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9e8689d4d08e41459e58226119f0fba92022-12-21T17:16:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m200m20110.1107/S1600536812002218trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrateIbrahim Göker ZamanNagihan Çaylak DelibaşHacali NecefoğluTuncer HökelekThe asymmetric unit of the title compound, [Ni(C6H6N2O)2(H2O)4](C7H5O3)2·4H2O, contains one-half of the complex cation with the NiII ion located on an inversion center, a 3-hydroxybenzoate counter-anion and two uncoordinated water molecules. Four water O atoms in the equatorial plane around the NiII ion [Ni—O = 2.052 (2) and 2.079 (2) Å] form a slightly distorted square-planar arrangement, which is completed up to a distorted octahedron by the two N atoms [Ni—N = 2.075 (3) Å] from two isonicotinamide ligands. In the anion, the carboxylate group is twisted from the attached benzene ring by 8.8 (3)°. In the crystal, a three-dimensional hydrogen-bonding network, formed by classical O—H...O and N—H...O hydrogen bonds, consolidates the crystal packing, which also exhibits π–π interactions between the benzene and pyridine rings, with centroid–centroid distances of 3.455 (2) and 3.621 (2) Å, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536812002218 |
| spellingShingle | Ibrahim Göker Zaman Nagihan Çaylak Delibaş Hacali Necefoğlu Tuncer Hökelek trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate Acta Crystallographica Section E |
| title | trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate |
| title_full | trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate |
| title_fullStr | trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate |
| title_full_unstemmed | trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate |
| title_short | trans-Tetraaquabis(isonicotinamide-κN1)nickel(II) bis(3-hydroxybenzoate) tetrahydrate |
| title_sort | trans tetraaquabis isonicotinamide amp 954 n1 nickel ii bis 3 hydroxybenzoate tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002218 |
| work_keys_str_mv | AT ibrahimgamp246kerzaman transtetraaquabisisonicotinamideamp954n1nickeliibis3hydroxybenzoatetetrahydrate AT nagihanamp199aylakdelibaamp351 transtetraaquabisisonicotinamideamp954n1nickeliibis3hydroxybenzoatetetrahydrate AT hacalinecefoamp287lu transtetraaquabisisonicotinamideamp954n1nickeliibis3hydroxybenzoatetetrahydrate AT tuncerhamp246kelek transtetraaquabisisonicotinamideamp954n1nickeliibis3hydroxybenzoatetetrahydrate |